Dynamic Modeling of Non-equilibrium Latex Particle Morphology Development During Seeded Emulsion Polymerization.
(2003) In Polymer Reaction Engineering 11(4). p.589-625- Abstract
- We have developed software to simulate the development of non-equilibrium latex particle morphologies produced by seeded emulsion polymerization. The diffusion of second stage polymer radicals within seed particles controls the development of morphology in a large number of systems. Knowledge of the conditions present within the latex particles during the reaction is required in order to model this diffusion process, and this makes it necessary to first simulate the kinetics of the polymerization. The program considers both the water phase and particle phase reactions, and can simulate polymerizations carried out under either batch or semi-batch conditions. The model predictions agree well with experimental results both in terms of the... (More)
- We have developed software to simulate the development of non-equilibrium latex particle morphologies produced by seeded emulsion polymerization. The diffusion of second stage polymer radicals within seed particles controls the development of morphology in a large number of systems. Knowledge of the conditions present within the latex particles during the reaction is required in order to model this diffusion process, and this makes it necessary to first simulate the kinetics of the polymerization. The program considers both the water phase and particle phase reactions, and can simulate polymerizations carried out under either batch or semi-batch conditions. The model predictions agree well with experimental results both in terms of the polymerization kinetics and the development of particle morphology. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/129533
- author
- Karlsson, Ola LU ; Stubbs, J M ; Carrier, R H and Sundberg, D C
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Polymer Reaction Engineering
- volume
- 11
- issue
- 4
- pages
- 589 - 625
- publisher
- Marcel Dekker
- external identifiers
-
- wos:000187349800004
- scopus:0347541162
- ISSN
- 1054-3414
- DOI
- 10.1081/PRE-120026365
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041), Department of Chemistry (011001220)
- id
- a8d079d2-0b7c-4c87-8e1f-e4343883b18a (old id 129533)
- date added to LUP
- 2016-04-01 16:40:46
- date last changed
- 2022-01-28 21:23:06
@article{a8d079d2-0b7c-4c87-8e1f-e4343883b18a,
abstract = {{We have developed software to simulate the development of non-equilibrium latex particle morphologies produced by seeded emulsion polymerization. The diffusion of second stage polymer radicals within seed particles controls the development of morphology in a large number of systems. Knowledge of the conditions present within the latex particles during the reaction is required in order to model this diffusion process, and this makes it necessary to first simulate the kinetics of the polymerization. The program considers both the water phase and particle phase reactions, and can simulate polymerizations carried out under either batch or semi-batch conditions. The model predictions agree well with experimental results both in terms of the polymerization kinetics and the development of particle morphology.}},
author = {{Karlsson, Ola and Stubbs, J M and Carrier, R H and Sundberg, D C}},
issn = {{1054-3414}},
language = {{eng}},
number = {{4}},
pages = {{589--625}},
publisher = {{Marcel Dekker}},
series = {{Polymer Reaction Engineering}},
title = {{Dynamic Modeling of Non-equilibrium Latex Particle Morphology Development During Seeded Emulsion Polymerization.}},
url = {{http://dx.doi.org/10.1081/PRE-120026365}},
doi = {{10.1081/PRE-120026365}},
volume = {{11}},
year = {{2003}},
}