Direct supercritical fluid extraction of alkylphenols from spiked and wastewater samples using extraction cells equipped with hydrophobic membrane-assemblies
(2004) In Journal of Liquid Chromatography & Related Technologies 27(18). p.2871-2888- Abstract
- Akylphenols (4-nonylphenol, 4-(1,1,3,3-tetramethylbutyl)-phenol and 2,6-bis(1,1-dimethylethyl)-4-ethylphenol) have been directly extracted from water samples using neat supercritical carbon dioxide and collected on an octadecyl silica (ODS) solid phase trap. The extraction cells were equipped with home-built assemblies containing hydrophobic membranes. The assemblies were inserted at each end of the extraction cell to maintain the water sample inside the extraction cell. In this case, no sample pretreatment step, such as freeze-drying or solid phase extraction (SPE) of the water samples, was needed prior to the supercritical fluid extraction (SFE). Distilled water, spiked with an alkylphenol standard solution at a level of 25 mg/L, was... (More)
- Akylphenols (4-nonylphenol, 4-(1,1,3,3-tetramethylbutyl)-phenol and 2,6-bis(1,1-dimethylethyl)-4-ethylphenol) have been directly extracted from water samples using neat supercritical carbon dioxide and collected on an octadecyl silica (ODS) solid phase trap. The extraction cells were equipped with home-built assemblies containing hydrophobic membranes. The assemblies were inserted at each end of the extraction cell to maintain the water sample inside the extraction cell. In this case, no sample pretreatment step, such as freeze-drying or solid phase extraction (SPE) of the water samples, was needed prior to the supercritical fluid extraction (SFE). Distilled water, spiked with an alkylphenol standard solution at a level of 25 mg/L, was used as a model sample to investigate extraction efficiency as well as collection capability. To obtain quantitative recoveries, a fractionated extraction/clution procedure was adopted. The alkylphenols were finally determined in a leachate water sample and in an industrial effluent sample, where the levels were in the range of 0.2-10 mg/L. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/138380
- author
- Sparr Eskilsson, Cecilia LU ; Agren, A ; Mathiasson, Lennart LU and Björklund, Erland LU
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Alkylphenols, Aqueous samples, Direct supercritical fluid extraction
- in
- Journal of Liquid Chromatography & Related Technologies
- volume
- 27
- issue
- 18
- pages
- 2871 - 2888
- publisher
- Taylor & Francis
- external identifiers
-
- wos:000224435800005
- scopus:5444272480
- ISSN
- 1082-6076
- DOI
- 10.1081/JLC-200030500
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Analytical Chemistry (S/LTH) (011001004)
- id
- 2c189be4-8938-4800-b01c-9592a40f6b4d (old id 138380)
- date added to LUP
- 2016-04-01 15:57:14
- date last changed
- 2022-01-28 08:16:59
@article{2c189be4-8938-4800-b01c-9592a40f6b4d,
abstract = {{Akylphenols (4-nonylphenol, 4-(1,1,3,3-tetramethylbutyl)-phenol and 2,6-bis(1,1-dimethylethyl)-4-ethylphenol) have been directly extracted from water samples using neat supercritical carbon dioxide and collected on an octadecyl silica (ODS) solid phase trap. The extraction cells were equipped with home-built assemblies containing hydrophobic membranes. The assemblies were inserted at each end of the extraction cell to maintain the water sample inside the extraction cell. In this case, no sample pretreatment step, such as freeze-drying or solid phase extraction (SPE) of the water samples, was needed prior to the supercritical fluid extraction (SFE). Distilled water, spiked with an alkylphenol standard solution at a level of 25 mg/L, was used as a model sample to investigate extraction efficiency as well as collection capability. To obtain quantitative recoveries, a fractionated extraction/clution procedure was adopted. The alkylphenols were finally determined in a leachate water sample and in an industrial effluent sample, where the levels were in the range of 0.2-10 mg/L.}},
author = {{Sparr Eskilsson, Cecilia and Agren, A and Mathiasson, Lennart and Björklund, Erland}},
issn = {{1082-6076}},
keywords = {{Alkylphenols; Aqueous samples; Direct supercritical fluid extraction}},
language = {{eng}},
number = {{18}},
pages = {{2871--2888}},
publisher = {{Taylor & Francis}},
series = {{Journal of Liquid Chromatography & Related Technologies}},
title = {{Direct supercritical fluid extraction of alkylphenols from spiked and wastewater samples using extraction cells equipped with hydrophobic membrane-assemblies}},
url = {{http://dx.doi.org/10.1081/JLC-200030500}},
doi = {{10.1081/JLC-200030500}},
volume = {{27}},
year = {{2004}},
}