Structure investigation of Ti-IV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane
(2004) In Chemistry: A European Journal 10(1). p.182-189- Abstract
- The complexes formed by the reaction of [Ti(OiPr)(4)] and bicyclo-octanediols (BODOLs) 1 and 2 (1:1) are useful as chiral catalysts in asymmetric reductions and were investigated by H-1 NMR spectroscopy and computational methods. A consistent picture emerged of head-to-tail dimers being kept together via a Ti-O-Ti-O mu-oxo bridge similar to the Ti-tartrates but different from the corresponding Ti-BINOLates and Ti-TADDOLates.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/139472
- author
- Sarvary, Ian LU ; Norrby, P-O and Frejd, Torbjörn LU
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemistry: A European Journal
- volume
- 10
- issue
- 1
- pages
- 182 - 189
- publisher
- Wiley-Blackwell
- external identifiers
-
- wos:000188087800018
- pmid:14695563
- scopus:0346458585
- ISSN
- 1521-3765
- DOI
- 10.1002/chem.200305202
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 960e9b68-d84e-438d-87fb-ee35adc2a226 (old id 139472)
- date added to LUP
- 2016-04-01 17:01:05
- date last changed
- 2022-06-04 01:17:33
@article{960e9b68-d84e-438d-87fb-ee35adc2a226, abstract = {{The complexes formed by the reaction of [Ti(OiPr)(4)] and bicyclo-octanediols (BODOLs) 1 and 2 (1:1) are useful as chiral catalysts in asymmetric reductions and were investigated by H-1 NMR spectroscopy and computational methods. A consistent picture emerged of head-to-tail dimers being kept together via a Ti-O-Ti-O mu-oxo bridge similar to the Ti-tartrates but different from the corresponding Ti-BINOLates and Ti-TADDOLates.}}, author = {{Sarvary, Ian and Norrby, P-O and Frejd, Torbjörn}}, issn = {{1521-3765}}, language = {{eng}}, number = {{1}}, pages = {{182--189}}, publisher = {{Wiley-Blackwell}}, series = {{Chemistry: A European Journal}}, title = {{Structure investigation of Ti-IV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane}}, url = {{http://dx.doi.org/10.1002/chem.200305202}}, doi = {{10.1002/chem.200305202}}, volume = {{10}}, year = {{2004}}, }