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Structure investigation of Ti-IV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane

Sarvary, Ian LU ; Norrby, P-O and Frejd, Torbjörn LU (2004) In Chemistry: A European Journal 10(1). p.182-189
Abstract
The complexes formed by the reaction of [Ti(OiPr)(4)] and bicyclo-octanediols (BODOLs) 1 and 2 (1:1) are useful as chiral catalysts in asymmetric reductions and were investigated by H-1 NMR spectroscopy and computational methods. A consistent picture emerged of head-to-tail dimers being kept together via a Ti-O-Ti-O mu-oxo bridge similar to the Ti-tartrates but different from the corresponding Ti-BINOLates and Ti-TADDOLates.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemistry: A European Journal
volume
10
issue
1
pages
182 - 189
publisher
Wiley-Blackwell
external identifiers
  • wos:000188087800018
  • pmid:14695563
  • scopus:0346458585
ISSN
1521-3765
DOI
10.1002/chem.200305202
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
960e9b68-d84e-438d-87fb-ee35adc2a226 (old id 139472)
date added to LUP
2016-04-01 17:01:05
date last changed
2022-06-04 01:17:33
@article{960e9b68-d84e-438d-87fb-ee35adc2a226,
  abstract     = {{The complexes formed by the reaction of [Ti(OiPr)(4)] and bicyclo-octanediols (BODOLs) 1 and 2 (1:1) are useful as chiral catalysts in asymmetric reductions and were investigated by H-1 NMR spectroscopy and computational methods. A consistent picture emerged of head-to-tail dimers being kept together via a Ti-O-Ti-O mu-oxo bridge similar to the Ti-tartrates but different from the corresponding Ti-BINOLates and Ti-TADDOLates.}},
  author       = {{Sarvary, Ian and Norrby, P-O and Frejd, Torbjörn}},
  issn         = {{1521-3765}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{182--189}},
  publisher    = {{Wiley-Blackwell}},
  series       = {{Chemistry: A European Journal}},
  title        = {{Structure investigation of Ti-IV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane}},
  url          = {{http://dx.doi.org/10.1002/chem.200305202}},
  doi          = {{10.1002/chem.200305202}},
  volume       = {{10}},
  year         = {{2004}},
}