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Structural Impact of Platinum on the Incommensurably Modulated γ-Brass Related Composite Structure Pd(15)Zn(54).

Jana, Partha LU and Lidin, Sven LU (2012) In Inorganic Chemistry 51(18). p.9893-9901
Abstract
The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of... (More)
The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of Zn atoms running along the center of the column. (Less)
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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Inorganic Chemistry
volume
51
issue
18
pages
9893 - 9901
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000308778000037
  • pmid:22950831
  • scopus:84866396845
  • pmid:22950831
ISSN
1520-510X
DOI
10.1021/ic301326p
language
English
LU publication?
yes
id
ac701191-5868-4d5d-abbc-e02870623cfa (old id 3124287)
date added to LUP
2016-04-01 11:13:54
date last changed
2022-01-26 06:24:19
@article{ac701191-5868-4d5d-abbc-e02870623cfa,
  abstract     = {{The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of Zn atoms running along the center of the column.}},
  author       = {{Jana, Partha and Lidin, Sven}},
  issn         = {{1520-510X}},
  language     = {{eng}},
  number       = {{18}},
  pages        = {{9893--9901}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Inorganic Chemistry}},
  title        = {{Structural Impact of Platinum on the Incommensurably Modulated γ-Brass Related Composite Structure Pd(15)Zn(54).}},
  url          = {{http://dx.doi.org/10.1021/ic301326p}},
  doi          = {{10.1021/ic301326p}},
  volume       = {{51}},
  year         = {{2012}},
}