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Crystalline Iron Oxohalide Nanotube Pea Pods

Zimmermann, Iwan ; Johnsson, Mats and Lidin, Sven LU (2012) In European Journal of Inorganic Chemistry p.3971-3974
Abstract
Compounds Fe7Sb3(PO4)3O6Cl3 and Fe7Sb3(PO4)3O6Br3 are the first iron phosphates containing SbIII. They were synthesized by chemical vapor transport reactions, and their crystal structures were characterized by single-crystal X-ray diffraction. The compounds are isostructural and crystallize in the orthorhombic space group Pnma. Tubular Fe7(PO4)3O6X3 units (X = Cl, Br) are linked by SbO4 groups to build up a framework. The tubular units consist of an outer part made up of [FeO5X] octahedra where the Fe atoms are arranged to resemble a nanotube. Inside the tubes there are phosphate groups, and at the very center there is a chain of face-sharing [FeO6] octahedra.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Oxohalides, Structure elucidation, Nanostructures, Iron, Antimony
in
European Journal of Inorganic Chemistry
issue
25
pages
3971 - 3974
publisher
John Wiley & Sons Inc.
external identifiers
  • wos:000307950500002
  • scopus:84865575393
ISSN
1099-0682
DOI
10.1002/ejic.201200205
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
69ad1101-16dd-449d-a595-504b4f18845e (old id 3139215)
date added to LUP
2016-04-01 09:52:39
date last changed
2022-01-25 17:35:52
@article{69ad1101-16dd-449d-a595-504b4f18845e,
  abstract     = {{Compounds Fe7Sb3(PO4)3O6Cl3 and Fe7Sb3(PO4)3O6Br3 are the first iron phosphates containing SbIII. They were synthesized by chemical vapor transport reactions, and their crystal structures were characterized by single-crystal X-ray diffraction. The compounds are isostructural and crystallize in the orthorhombic space group Pnma. Tubular Fe7(PO4)3O6X3 units (X = Cl, Br) are linked by SbO4 groups to build up a framework. The tubular units consist of an outer part made up of [FeO5X] octahedra where the Fe atoms are arranged to resemble a nanotube. Inside the tubes there are phosphate groups, and at the very center there is a chain of face-sharing [FeO6] octahedra.}},
  author       = {{Zimmermann, Iwan and Johnsson, Mats and Lidin, Sven}},
  issn         = {{1099-0682}},
  keywords     = {{Oxohalides; Structure elucidation; Nanostructures; Iron; Antimony}},
  language     = {{eng}},
  number       = {{25}},
  pages        = {{3971--3974}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{European Journal of Inorganic Chemistry}},
  title        = {{Crystalline Iron Oxohalide Nanotube Pea Pods}},
  url          = {{http://dx.doi.org/10.1002/ejic.201200205}},
  doi          = {{10.1002/ejic.201200205}},
  year         = {{2012}},
}