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Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate

Xiong, Y ; Tong, ML ; An, TC and Karlsson, Hans LU (2001) In Acta Crystallographica. Section C: Crystal Structure Communications 57. p.1385-1387
Abstract
In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.
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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
57
pages
1385 - 1387
publisher
International Union of Crystallography
external identifiers
  • wos:000172548200008
  • scopus:0035683977
ISSN
0108-2701
DOI
10.1107/S0108270101015116
language
English
LU publication?
yes
id
6d0ac6e2-d2b5-456f-a357-dd40d1602d54 (old id 3915885)
date added to LUP
2016-04-01 16:00:33
date last changed
2023-09-04 10:46:46
@article{6d0ac6e2-d2b5-456f-a357-dd40d1602d54,
  abstract     = {{In the neutral title complex, [Cu(C3H2O4)(C5H8N2)(2-)(H2O)]. 2H(2)O or [Cu(mal)(dmp)(2)(H2O)]. 2H(2)O (mal is malonate and dmp is 3,5-dimethyl-1H-pyrazole), the Cu-II ion, in a slightly distorted square-pyramidal geometry, is coordinated by two O atoms of the bidentate malonate, the O atom of the water ligand and two N atoms from the two 3,5-dimethylpyrazole ligands. The mean Cu-N bond length is 2.007 (6) Angstrom, longer than the Cu-O-mal bonds [1.950 (5) Angstrom]. The apical position is occupied by a relatively strongly coordinated water molecule [Cu-O-water 2.288 (5) Angstrom]. The crystal structure is characterized by the layer motif of a hydrogen-bonded network.}},
  author       = {{Xiong, Y and Tong, ML and An, TC and Karlsson, Hans}},
  issn         = {{0108-2701}},
  language     = {{eng}},
  pages        = {{1385--1387}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica. Section C: Crystal Structure Communications}},
  title        = {{Aquabis(3,5-dimethyl-1H-pyrazole-kappa N-2)(malonato-kappa O-2,O ')copper(II) dihydrate}},
  url          = {{http://dx.doi.org/10.1107/S0108270101015116}},
  doi          = {{10.1107/S0108270101015116}},
  volume       = {{57}},
  year         = {{2001}},
}