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Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Mitra, Mainak LU ; Lloret-Fillol, Julio ; Haukka, Matti ; Costas, Miquel and Nordlander, Ebbe LU (2014) In Chemical Communications 50(12). p.1408-1410
Abstract
A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
50
issue
12
pages
1408 - 1410
publisher
Royal Society of Chemistry
external identifiers
  • wos:000329925900002
  • pmid:24270942
  • scopus:84892609738
ISSN
1364-548X
DOI
10.1039/c3cc47830k
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
f85e3012-5766-443b-a1ec-56255639a76d (old id 4178960)
date added to LUP
2016-04-01 09:54:25
date last changed
2022-02-02 04:00:26
@article{f85e3012-5766-443b-a1ec-56255639a76d,
  abstract     = {{A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.}},
  author       = {{Mitra, Mainak and Lloret-Fillol, Julio and Haukka, Matti and Costas, Miquel and Nordlander, Ebbe}},
  issn         = {{1364-548X}},
  language     = {{eng}},
  number       = {{12}},
  pages        = {{1408--1410}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Chemical Communications}},
  title        = {{Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.}},
  url          = {{http://dx.doi.org/10.1039/c3cc47830k}},
  doi          = {{10.1039/c3cc47830k}},
  volume       = {{50}},
  year         = {{2014}},
}