In Situ X-ray Polymerization: From Swollen Lamellae to Polymer-Surfactant Complexes
(2014) In The Journal of Physical Chemistry Part B 118(4). p.1159-1167- Abstract
- The influence of the monomer diallyldimethylammonium chloride (D) on the lamellar liquid crystal formed by the anionic surfactant aerosol OT (AOT) and water is investigated, determining the lamellar spacings by SAXS and the quadrupolar splittings by deuterium NMR, as a function of the D or AOT concentrations. The cationic monomer D induces a destabilization of the AOT lamellar structure such that, at a critical concentration higher than 5 wt %, macroscopic phase separation takes place. When the monomer, which is dissolved in the AOT lamellae, is polymerized in situ by X-ray initiation, a new collapsed lamellar phase appears, corresponding to the complexation of the surfactant with the resulting polymer. A theoretical model is employed to... (More)
- The influence of the monomer diallyldimethylammonium chloride (D) on the lamellar liquid crystal formed by the anionic surfactant aerosol OT (AOT) and water is investigated, determining the lamellar spacings by SAXS and the quadrupolar splittings by deuterium NMR, as a function of the D or AOT concentrations. The cationic monomer D induces a destabilization of the AOT lamellar structure such that, at a critical concentration higher than 5 wt %, macroscopic phase separation takes place. When the monomer, which is dissolved in the AOT lamellae, is polymerized in situ by X-ray initiation, a new collapsed lamellar phase appears, corresponding to the complexation of the surfactant with the resulting polymer. A theoretical model is employed to analyze the variation of the interactions between the AOT bilayers and the stability of the lamellar structure. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/5104425
- author
- Agzenai, Y ; Lindman, Björn LU ; Alfredsson, Viveka LU ; Topgaard, Daniel LU ; Renamyor, C.S. and Pacios, I. E.
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of Physical Chemistry Part B
- volume
- 118
- issue
- 4
- pages
- 1159 - 1167
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:84893434078
- pmid:24410395
- wos:000330610400032
- ISSN
- 1520-5207
- DOI
- 10.1021/jp411894e
- language
- English
- LU publication?
- yes
- id
- 6b0138fd-e941-4965-9362-bc6784d15eab (old id 5104425)
- date added to LUP
- 2016-04-01 10:30:55
- date last changed
- 2022-03-12 06:35:59
@article{6b0138fd-e941-4965-9362-bc6784d15eab,
abstract = {{The influence of the monomer diallyldimethylammonium chloride (D) on the lamellar liquid crystal formed by the anionic surfactant aerosol OT (AOT) and water is investigated, determining the lamellar spacings by SAXS and the quadrupolar splittings by deuterium NMR, as a function of the D or AOT concentrations. The cationic monomer D induces a destabilization of the AOT lamellar structure such that, at a critical concentration higher than 5 wt %, macroscopic phase separation takes place. When the monomer, which is dissolved in the AOT lamellae, is polymerized in situ by X-ray initiation, a new collapsed lamellar phase appears, corresponding to the complexation of the surfactant with the resulting polymer. A theoretical model is employed to analyze the variation of the interactions between the AOT bilayers and the stability of the lamellar structure.}},
author = {{Agzenai, Y and Lindman, Björn and Alfredsson, Viveka and Topgaard, Daniel and Renamyor, C.S. and Pacios, I. E.}},
issn = {{1520-5207}},
language = {{eng}},
number = {{4}},
pages = {{1159--1167}},
publisher = {{The American Chemical Society (ACS)}},
series = {{The Journal of Physical Chemistry Part B}},
title = {{In Situ X-ray Polymerization: From Swollen Lamellae to Polymer-Surfactant Complexes}},
url = {{http://dx.doi.org/10.1021/jp411894e}},
doi = {{10.1021/jp411894e}},
volume = {{118}},
year = {{2014}},
}