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Chlorine-Free Synthesis of Organic Alkyl Carbonates and Five- and Six-Membered Cyclic Carbonates

Pyo, Sang Hyun LU and Hatti-Kaul, Rajni LU (2016) In Advanced Synthesis & Catalysis 358(5). p.834-839
Abstract

This report presents a new, one-pot, facile, selective and green method for methoxycarbonylation of alcohols and synthesis of five- and six-membered cyclic carbonates from corresponding alcohols with dimethyl carbonate (DMC) in the presence of molecular sieves without any additional solvent and catalyst. Syntheses of bifunctional structures comprising a six-membered cyclic carbonate with allyl ether and methacrylate groups, respectively, for different polymerization modes, were also achieved and showed reproducibility on up-scaling the processes.

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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
alkyl carbonates, chlorine-free reactions, cyclic carbonates, one-pot carbonylation
in
Advanced Synthesis & Catalysis
volume
358
issue
5
pages
6 pages
publisher
John Wiley & Sons Inc.
external identifiers
  • wos:000372132100019
  • scopus:84959297459
ISSN
1615-4169
DOI
10.1002/adsc.201500654
language
English
LU publication?
yes
id
5e97e14e-52f6-44aa-8716-330530d74c95
date added to LUP
2016-06-28 12:49:34
date last changed
2024-01-04 09:07:12
@article{5e97e14e-52f6-44aa-8716-330530d74c95,
  abstract     = {{<p>This report presents a new, one-pot, facile, selective and green method for methoxycarbonylation of alcohols and synthesis of five- and six-membered cyclic carbonates from corresponding alcohols with dimethyl carbonate (DMC) in the presence of molecular sieves without any additional solvent and catalyst. Syntheses of bifunctional structures comprising a six-membered cyclic carbonate with allyl ether and methacrylate groups, respectively, for different polymerization modes, were also achieved and showed reproducibility on up-scaling the processes.</p>}},
  author       = {{Pyo, Sang Hyun and Hatti-Kaul, Rajni}},
  issn         = {{1615-4169}},
  keywords     = {{alkyl carbonates; chlorine-free reactions; cyclic carbonates; one-pot carbonylation}},
  language     = {{eng}},
  month        = {{03}},
  number       = {{5}},
  pages        = {{834--839}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{Advanced Synthesis & Catalysis}},
  title        = {{Chlorine-Free Synthesis of Organic Alkyl Carbonates and Five- and Six-Membered Cyclic Carbonates}},
  url          = {{http://dx.doi.org/10.1002/adsc.201500654}},
  doi          = {{10.1002/adsc.201500654}},
  volume       = {{358}},
  year         = {{2016}},
}