Evolution of CuI/Graphene/Ni(111) System during Vacuum Annealing
(2015) In Journal of Physical Chemistry C 119(22). p.12434-12444- Abstract
- We present a combined core-level spectroscopy and low-energy electron diffraction study of the evolution of thin CuI layers on graphene/Ni(111) during annealing. It has been found that the annealing of the CuI/graphene/Ni(111) system up to 160 degrees C results in the formation of an ordered CuI overlayer with a (root 3 x root 3) R30 degrees structure on top of the graphene surface. At annealing temperatures of about 180 degrees C or higher, the CuI overlayer decomposes with a simultaneous intercalation of Cu and I atoms underneath the graphene monolayer on Ni(111). Nearly complete intercalation of graphene by Cu and I atoms can be achieved by deposition of about 20 angstrom of CuI, followed by annealing at 200 degrees C. The intercalated... (More)
- We present a combined core-level spectroscopy and low-energy electron diffraction study of the evolution of thin CuI layers on graphene/Ni(111) during annealing. It has been found that the annealing of the CuI/graphene/Ni(111) system up to 160 degrees C results in the formation of an ordered CuI overlayer with a (root 3 x root 3) R30 degrees structure on top of the graphene surface. At annealing temperatures of about 180 degrees C or higher, the CuI overlayer decomposes with a simultaneous intercalation of Cu and I atoms underneath the graphene monolayer on Ni(111). Nearly complete intercalation of graphene by Cu and I atoms can be achieved by deposition of about 20 angstrom of CuI, followed by annealing at 200 degrees C. The intercalated graphene layer is p-doped due to interfacial iodine atoms. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/7605052
- author
- Generaloy, Alexander V. ; Simonov, Konstantin LU ; Vinogradov, Nikolay A. ; Zagrebina, Elena M. ; Martensson, Nils ; Preobrajenski, Alexei LU and Vinogradoy, Alexander S.
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physical Chemistry C
- volume
- 119
- issue
- 22
- pages
- 12434 - 12444
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000355891600035
- scopus:84930958825
- ISSN
- 1932-7447
- DOI
- 10.1021/acs.jpcc.5b02390
- language
- English
- LU publication?
- yes
- id
- 81ba3caf-ee9c-4546-b21c-ba1c6a64bb36 (old id 7605052)
- date added to LUP
- 2016-04-01 10:16:43
- date last changed
- 2022-01-25 21:39:25
@article{81ba3caf-ee9c-4546-b21c-ba1c6a64bb36,
abstract = {{We present a combined core-level spectroscopy and low-energy electron diffraction study of the evolution of thin CuI layers on graphene/Ni(111) during annealing. It has been found that the annealing of the CuI/graphene/Ni(111) system up to 160 degrees C results in the formation of an ordered CuI overlayer with a (root 3 x root 3) R30 degrees structure on top of the graphene surface. At annealing temperatures of about 180 degrees C or higher, the CuI overlayer decomposes with a simultaneous intercalation of Cu and I atoms underneath the graphene monolayer on Ni(111). Nearly complete intercalation of graphene by Cu and I atoms can be achieved by deposition of about 20 angstrom of CuI, followed by annealing at 200 degrees C. The intercalated graphene layer is p-doped due to interfacial iodine atoms.}},
author = {{Generaloy, Alexander V. and Simonov, Konstantin and Vinogradov, Nikolay A. and Zagrebina, Elena M. and Martensson, Nils and Preobrajenski, Alexei and Vinogradoy, Alexander S.}},
issn = {{1932-7447}},
language = {{eng}},
number = {{22}},
pages = {{12434--12444}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Journal of Physical Chemistry C}},
title = {{Evolution of CuI/Graphene/Ni(111) System during Vacuum Annealing}},
url = {{http://dx.doi.org/10.1021/acs.jpcc.5b02390}},
doi = {{10.1021/acs.jpcc.5b02390}},
volume = {{119}},
year = {{2015}},
}