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Synthesis and single crystal study of CuMn3As2 and Cu2Mn4As3

Uhlirova, Klara ; Tarasenko, Robert ; Martinez, Francisco LU ; Vondrackova, Barbora and Matej, Zdenek LU orcid (2015) In Journal of Alloys and Compounds 650. p.224-227
Abstract
We report on single-crystal growth, and crystal structure of CuMn3As2 and Cu2Mn4As3 compounds. Magnetic properties of Cu2Mn4As3 were studied in temperature range between 2 and 400 K. The single crystals were prepared from bismuth flux and characterized by means of single crystals diffraction, electron-microprobe analysis, magnetic and resistivity measurements. Crystal structures of CuMn3As2 and Cu2Mn4As3 were determined by synchrotron radiation x-ray diffraction experiments at 100 K. The CuMn3As2 and Cu2Mn4As3 crystallize in an orthorhombic structure with very similar lattice parameters. Magnetic and resistivity measurements on Cu2Mn4As3 suggest existence of long range magnetic order below 315 K with another magnetic transition at 45 K.... (More)
We report on single-crystal growth, and crystal structure of CuMn3As2 and Cu2Mn4As3 compounds. Magnetic properties of Cu2Mn4As3 were studied in temperature range between 2 and 400 K. The single crystals were prepared from bismuth flux and characterized by means of single crystals diffraction, electron-microprobe analysis, magnetic and resistivity measurements. Crystal structures of CuMn3As2 and Cu2Mn4As3 were determined by synchrotron radiation x-ray diffraction experiments at 100 K. The CuMn3As2 and Cu2Mn4As3 crystallize in an orthorhombic structure with very similar lattice parameters. Magnetic and resistivity measurements on Cu2Mn4As3 suggest existence of long range magnetic order below 315 K with another magnetic transition at 45 K. (C) 2015 Elsevier B.V. All rights reserved. (Less)
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Antiferromagnetism, Crystal structure, CuMn3As2, CuMnAs
in
Journal of Alloys and Compounds
volume
650
pages
224 - 227
publisher
Elsevier
external identifiers
  • wos:000361519300033
  • scopus:84938909160
ISSN
0925-8388
DOI
10.1016/j.jallcom.2015.07.208
language
English
LU publication?
yes
id
bc9545cb-5f39-4dc2-99cb-c1c3c3aa5794 (old id 8058429)
date added to LUP
2016-04-01 14:42:24
date last changed
2023-08-16 12:58:49
@article{bc9545cb-5f39-4dc2-99cb-c1c3c3aa5794,
  abstract     = {{We report on single-crystal growth, and crystal structure of CuMn3As2 and Cu2Mn4As3 compounds. Magnetic properties of Cu2Mn4As3 were studied in temperature range between 2 and 400 K. The single crystals were prepared from bismuth flux and characterized by means of single crystals diffraction, electron-microprobe analysis, magnetic and resistivity measurements. Crystal structures of CuMn3As2 and Cu2Mn4As3 were determined by synchrotron radiation x-ray diffraction experiments at 100 K. The CuMn3As2 and Cu2Mn4As3 crystallize in an orthorhombic structure with very similar lattice parameters. Magnetic and resistivity measurements on Cu2Mn4As3 suggest existence of long range magnetic order below 315 K with another magnetic transition at 45 K. (C) 2015 Elsevier B.V. All rights reserved.}},
  author       = {{Uhlirova, Klara and Tarasenko, Robert and Martinez, Francisco and Vondrackova, Barbora and Matej, Zdenek}},
  issn         = {{0925-8388}},
  keywords     = {{Antiferromagnetism; Crystal structure; CuMn3As2; CuMnAs}},
  language     = {{eng}},
  pages        = {{224--227}},
  publisher    = {{Elsevier}},
  series       = {{Journal of Alloys and Compounds}},
  title        = {{Synthesis and single crystal study of CuMn3As2 and Cu2Mn4As3}},
  url          = {{http://dx.doi.org/10.1016/j.jallcom.2015.07.208}},
  doi          = {{10.1016/j.jallcom.2015.07.208}},
  volume       = {{650}},
  year         = {{2015}},
}