High-Quality Metal-Organic Framework Ultrathin Films for Electronically Active Interfaces.
(2016) In Journal of the American Chemical Society 138(8). p.2576-2584- Abstract
- Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration... (More)
- Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration of MOFs as active interfaces in electronic devices. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/8829244
- author
- Rubio-Giménez, Víctor ; Tatay, Sergio ; Volatron, Florence ; Martinez, Francisco LU ; Martí-Gastaldo, Carlos and Coronado, Eugenio
- organization
- publishing date
- 2016-02-05
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of the American Chemical Society
- volume
- 138
- issue
- 8
- pages
- 2576 - 2584
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- pmid:26847507
- scopus:84959573031
- wos:000371453700028
- pmid:26847507
- ISSN
- 1520-5126
- DOI
- 10.1021/jacs.5b09784
- language
- English
- LU publication?
- yes
- id
- d76f57c0-4a7f-4b1e-a87c-9830d9dbce49 (old id 8829244)
- date added to LUP
- 2016-04-01 13:54:03
- date last changed
- 2022-01-27 21:43:48
@article{d76f57c0-4a7f-4b1e-a87c-9830d9dbce49,
abstract = {{Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration of MOFs as active interfaces in electronic devices.}},
author = {{Rubio-Giménez, Víctor and Tatay, Sergio and Volatron, Florence and Martinez, Francisco and Martí-Gastaldo, Carlos and Coronado, Eugenio}},
issn = {{1520-5126}},
language = {{eng}},
month = {{02}},
number = {{8}},
pages = {{2576--2584}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Journal of the American Chemical Society}},
title = {{High-Quality Metal-Organic Framework Ultrathin Films for Electronically Active Interfaces.}},
url = {{http://dx.doi.org/10.1021/jacs.5b09784}},
doi = {{10.1021/jacs.5b09784}},
volume = {{138}},
year = {{2016}},
}