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Synthesis of α-Keto Amides by a Pyrrolidine/TEMPO-Mediated Oxidation of α-Keto Amines

Yu, Lu LU and Somfai, Peter LU (2016) In Synlett 27(18). p.2587-2590
Abstract

A mild procedure has been developed for the synthesis of α-keto amides by α-oxidation of the corresponding α-keto amines mediated by pyrrolidine and TEMPO. The method can also be applied to the synthesis of α-keto thioamides and α-keto amidines.

Please use this url to cite or link to this publication:
author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
amides, amines, catalysis, ketones, oxidation, thioamides
in
Synlett
volume
27
issue
18
article number
st-2016-b0315-l
pages
4 pages
publisher
Georg Thieme Verlag
external identifiers
  • scopus:84983020532
  • wos:000387254900012
ISSN
0936-5214
DOI
10.1055/s-0035-1562541
language
English
LU publication?
yes
id
e506a515-3f20-46d0-b7a5-acfbd0b7aa4d
date added to LUP
2016-11-18 15:29:39
date last changed
2024-04-19 12:54:58
@article{e506a515-3f20-46d0-b7a5-acfbd0b7aa4d,
  abstract     = {{<p>A mild procedure has been developed for the synthesis of α-keto amides by α-oxidation of the corresponding α-keto amines mediated by pyrrolidine and TEMPO. The method can also be applied to the synthesis of α-keto thioamides and α-keto amidines.</p>}},
  author       = {{Yu, Lu and Somfai, Peter}},
  issn         = {{0936-5214}},
  keywords     = {{amides; amines; catalysis; ketones; oxidation; thioamides}},
  language     = {{eng}},
  month        = {{11}},
  number       = {{18}},
  pages        = {{2587--2590}},
  publisher    = {{Georg Thieme Verlag}},
  series       = {{Synlett}},
  title        = {{Synthesis of α-Keto Amides by a Pyrrolidine/TEMPO-Mediated Oxidation of α-Keto Amines}},
  url          = {{http://dx.doi.org/10.1055/s-0035-1562541}},
  doi          = {{10.1055/s-0035-1562541}},
  volume       = {{27}},
  year         = {{2016}},
}