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In vitro study of Biodegradation in Mg-alloys by Isothermal Calorimetry

Kekare, Prasad Rajendra LU and Kulkarni, Akshat LU (2021) MMTM05 20211
Production and Materials Engineering
Abstract
Magnesium corrosion in an aqueous environment is a multi-layer, complex process. A literature survey shows significant gaps and the modelling work reported indicates a lack of clarity in understanding the corrosion process. Studies on the effects of impurities and interfacial compounds formed by selected alloying additions would help in filling some of these gaps.

Further, the evolution of hydrogen gas with the dissolution of magnesium may pose a threat to living cells in Biomedical Applications. As a result, it is critical to monitor Mg corrosion rates and investigate the impact of alloying elements. For clarity, an overview of the basic mechanisms of magnesium corrosion in an aqueous solution and the thermodynamic background is... (More)
Magnesium corrosion in an aqueous environment is a multi-layer, complex process. A literature survey shows significant gaps and the modelling work reported indicates a lack of clarity in understanding the corrosion process. Studies on the effects of impurities and interfacial compounds formed by selected alloying additions would help in filling some of these gaps.

Further, the evolution of hydrogen gas with the dissolution of magnesium may pose a threat to living cells in Biomedical Applications. As a result, it is critical to monitor Mg corrosion rates and investigate the impact of alloying elements. For clarity, an overview of the basic mechanisms of magnesium corrosion in an aqueous solution and the thermodynamic background is presented.

The project investigates the corrosion behaviour of three alloys (Mg-0.8Nd, Mg-0.2Zr & Mg-0.8Nd-0.2Zr) in a 0.9wt% NaCl solution using Isothermal calorimetry and the pressure measurement technique. Heat flow, and energy changes were monitored, providing the basis for understanding the corrosion process. Hydrogen gas evolution measurements were correlated with thermal power. Small changes in the corrosion process lead to noise-like variations in thermal power. The effect of alloying addition and heat treatment on corrosion rates have also been addressed in the present study. (Less)
Popular Abstract
Magnesium corrosion in an aqueous environment is a multi-layer, complex process. A literature survey shows significant gaps and the modelling work reported indicates a lack of clarity in understanding the corrosion process. Studies on the effects of impurities and interfacial compounds formed by selected alloying additions would help in filling some of these gaps.

Further, the evolution of hydrogen gas with the dissolution of magnesium may pose a threat to living cells in Biomedical Applications. As a result, it is critical to monitor Mg corrosion rates and investigate the impact of alloying elements. For clarity, an overview of the basic mechanisms of magnesium corrosion in an aqueous solution and the thermodynamic background is... (More)
Magnesium corrosion in an aqueous environment is a multi-layer, complex process. A literature survey shows significant gaps and the modelling work reported indicates a lack of clarity in understanding the corrosion process. Studies on the effects of impurities and interfacial compounds formed by selected alloying additions would help in filling some of these gaps.

Further, the evolution of hydrogen gas with the dissolution of magnesium may pose a threat to living cells in Biomedical Applications. As a result, it is critical to monitor Mg corrosion rates and investigate the impact of alloying elements. For clarity, an overview of the basic mechanisms of magnesium corrosion in an aqueous solution and the thermodynamic background is presented.

The project investigates the corrosion behaviour of three alloys (Mg-0.8Nd, Mg-0.2Zr & Mg-0.8Nd-0.2Zr) in a 0.9wt% NaCl solution using Isothermal calorimetry and the pressure measurement technique. Heat flow, and energy changes were monitored, providing the basis for understanding the corrosion process. Hydrogen gas evolution measurements were correlated with thermal power. Small changes in the corrosion process lead to noise-like variations in thermal power. The effect of alloying addition and heat treatment on corrosion rates have also been addressed in the present study. (Less)
Please use this url to cite or link to this publication:
author
Kekare, Prasad Rajendra LU and Kulkarni, Akshat LU
supervisor
organization
course
MMTM05 20211
year
type
H2 - Master's Degree (Two Years)
subject
keywords
Isothermal Calorimetry, Degradation of Mg Alloys, Supersaturated solid solution (SSSS), Corrosion rate, Aqueous corrosion.
report number
ISBN LUTFD2/TFMT--21/5065--SE
language
English
id
9054528
date added to LUP
2021-06-15 12:40:42
date last changed
2021-06-15 12:40:42
@misc{9054528,
  abstract     = {{Magnesium corrosion in an aqueous environment is a multi-layer, complex process. A literature survey shows significant gaps and the modelling work reported indicates a lack of clarity in understanding the corrosion process. Studies on the effects of impurities and interfacial compounds formed by selected alloying additions would help in filling some of these gaps. 

Further, the evolution of hydrogen gas with the dissolution of magnesium may pose a threat to living cells in Biomedical Applications. As a result, it is critical to monitor Mg corrosion rates and investigate the impact of alloying elements. For clarity, an overview of the basic mechanisms of magnesium corrosion in an aqueous solution and the thermodynamic background is presented.

The project investigates the corrosion behaviour of three alloys (Mg-0.8Nd, Mg-0.2Zr & Mg-0.8Nd-0.2Zr) in a 0.9wt% NaCl solution using Isothermal calorimetry and the pressure measurement technique. Heat flow, and energy changes were monitored, providing the basis for understanding the corrosion process. Hydrogen gas evolution measurements were correlated with thermal power. Small changes in the corrosion process lead to noise-like variations in thermal power. The effect of alloying addition and heat treatment on corrosion rates have also been addressed in the present study.}},
  author       = {{Kekare, Prasad Rajendra and Kulkarni, Akshat}},
  language     = {{eng}},
  note         = {{Student Paper}},
  title        = {{In vitro study of Biodegradation in Mg-alloys by Isothermal Calorimetry}},
  year         = {{2021}},
}