Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts
(2010) In Catalysis Today 157(1-4). p.33-38- Abstract
- Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1731160
- author
- Grasselli, R. K. ; Lugmair, C. G. ; Volpe Jr., A. F. ; Andersson, Arne LU and Burrington, J.D.
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- propylene, M1/M2, propane, acrylic acid
- in
- Catalysis Today
- volume
- 157
- issue
- 1-4
- pages
- 33 - 38
- publisher
- Elsevier
- external identifiers
-
- wos:000284502000006
- scopus:78049245357
- ISSN
- 0920-5861
- DOI
- 10.1016/j.cattod.2010.01.044
- language
- English
- LU publication?
- yes
- id
- 682839cc-1fc3-4488-8acc-0945eba4be89 (old id 1731160)
- date added to LUP
- 2016-04-01 13:55:44
- date last changed
- 2023-11-13 00:04:34
@article{682839cc-1fc3-4488-8acc-0945eba4be89, abstract = {{Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.}}, author = {{Grasselli, R. K. and Lugmair, C. G. and Volpe Jr., A. F. and Andersson, Arne and Burrington, J.D.}}, issn = {{0920-5861}}, keywords = {{propylene; M1/M2; propane; acrylic acid}}, language = {{eng}}, number = {{1-4}}, pages = {{33--38}}, publisher = {{Elsevier}}, series = {{Catalysis Today}}, title = {{Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts}}, url = {{http://dx.doi.org/10.1016/j.cattod.2010.01.044}}, doi = {{10.1016/j.cattod.2010.01.044}}, volume = {{157}}, year = {{2010}}, }