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The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption

Vinogradov, A. S.; Fedoseenko, S. I.; Krasnikov, S. A.; Preobrajenski, Alexei LU ; Sivkov, N. V. and Vyalikh, D. V. (2005) In Physica Scripta T115. p.510-512
Abstract
The near-edge fine structure of the F 1s absorption spectra of 3d metal fluorides was studied for the first time with high energy resolution. The spectra of these, the most ionic compounds of the 3d atoms, are analyzed comparing with the F 1s absorption spectrum of the molecular TiF62− anion in solid K2TiF6. The latter spectrum was afore interpreted considering the fluorine spectra of the molecular PF6− anion in a KPF6 crystal and of the gas-phase SF6 molecule. The low-energy empty electron states in the 3d metal fluorides are shown to be formed due to covalent mixing of the metal 3d and fluorine 2p electron states.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physica Scripta
volume
T115
pages
510 - 512
publisher
Institute of Physics Publishing Ltd.
external identifiers
  • WOS:000204272100151
  • Scopus:33749346739
ISSN
0031-8949
DOI
10.1238/Physica.Topical.115a00510
language
English
LU publication?
yes
id
c5f26666-dc0e-4cce-9ecb-d5b33a0264db (old id 976085)
date added to LUP
2009-07-27 15:16:58
date last changed
2016-10-13 04:38:10
@misc{c5f26666-dc0e-4cce-9ecb-d5b33a0264db,
  abstract     = {The near-edge fine structure of the F 1s absorption spectra of 3d metal fluorides was studied for the first time with high energy resolution. The spectra of these, the most ionic compounds of the 3d atoms, are analyzed comparing with the F 1s absorption spectrum of the molecular TiF62− anion in solid K2TiF6. The latter spectrum was afore interpreted considering the fluorine spectra of the molecular PF6− anion in a KPF6 crystal and of the gas-phase SF6 molecule. The low-energy empty electron states in the 3d metal fluorides are shown to be formed due to covalent mixing of the metal 3d and fluorine 2p electron states.},
  author       = {Vinogradov, A. S. and Fedoseenko, S. I. and Krasnikov, S. A. and Preobrajenski, Alexei and Sivkov, N. V. and Vyalikh, D. V.},
  issn         = {0031-8949},
  language     = {eng},
  pages        = {510--512},
  publisher    = {ARRAY(0x8dc5d88)},
  series       = {Physica Scripta},
  title        = {The hybridized M3d-F2p character of low-energy unoccupied electron states in 3d metal fluorides observed by F 1s absorption},
  url          = {http://dx.doi.org/10.1238/Physica.Topical.115a00510},
  volume       = {T115},
  year         = {2005},
}