Advanced

Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

Nilsson, Elna J K LU ; Hoff, Janus; Nielsen, Ole John and Johnson, Matthew S. (2010) In Chemical Physics Letters 494(4-6). p.160-162
Abstract

The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1. © 2010 Elsevier B.V. All rights reserved.

Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Physics Letters
volume
494
issue
4-6
pages
3 pages
publisher
Elsevier
external identifiers
  • Scopus:77955309603
ISSN
0009-2614
DOI
10.1016/j.cplett.2010.06.026
language
English
LU publication?
yes
id
bcdb277e-719a-4b37-ad0a-12073d8be0d3
date added to LUP
2016-10-04 10:33:13
date last changed
2016-11-14 12:48:23
@misc{bcdb277e-719a-4b37-ad0a-12073d8be0d3,
  abstract     = {<p>The reaction CHCl<sub>3</sub> + Cl → CCl<sub>3</sub> + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N<sub>2</sub> diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10<sup>-12</sup> exp((-1011 ± 24)/T) cm<sup>3</sup> molecule<sup>-1</sup> s<sup>-1</sup>. © 2010 Elsevier B.V. All rights reserved.</p>},
  author       = {Nilsson, Elna J K and Hoff, Janus and Nielsen, Ole John and Johnson, Matthew S.},
  issn         = {0009-2614},
  language     = {eng},
  month        = {07},
  number       = {4-6},
  pages        = {160--162},
  publisher    = {ARRAY(0x84ddb98)},
  series       = {Chemical Physics Letters},
  title        = {Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K},
  url          = {http://dx.doi.org/10.1016/j.cplett.2010.06.026},
  volume       = {494},
  year         = {2010},
}