Reactivity of TiS2 Anode towards Electrolytes in Aqueous Lithium-Ion Batteries
Zhang, Leiting ; Hou, Xu LU
; Edström, Kristina
and Berg, Erik J.
(2022)
In Batteries and Supercaps
5(12).
- Abstract
Aqueous rechargeable batteries are appealing alternatives for large-scale energy storage. Reversible cycling of high-energy aqueous batteries has been showcased using highly concentrated aqueous electrolytes, which lead to a significantly suppressed water activity and formation of a stable solid-electrolyte interphase (SEI). However, the high salt concentration inevitably raises the cost and compromises the environmental sustainability. Herein, we use layered TiS2 as a model anode to explore the feasibility of cycling aqueous cells in dilute electrolytes. By coupling three-electrode cycling data with online electrochemical mass spectrometry measurements, we depict the potential-dependent gas evolution from the cell in the... (More)
Aqueous rechargeable batteries are appealing alternatives for large-scale energy storage. Reversible cycling of high-energy aqueous batteries has been showcased using highly concentrated aqueous electrolytes, which lead to a significantly suppressed water activity and formation of a stable solid-electrolyte interphase (SEI). However, the high salt concentration inevitably raises the cost and compromises the environmental sustainability. Herein, we use layered TiS2 as a model anode to explore the feasibility of cycling aqueous cells in dilute electrolytes. By coupling three-electrode cycling data with online electrochemical mass spectrometry measurements, we depict the potential-dependent gas evolution from the cell in the absence of a stable SEI. We offer a comprehensive mechanistic understanding of the complex interfacial chemistry in dilute electrolytes, taking into account material reactivity and interfacial compatibility. Design strategies and research directions of layered-type electrodes for sustainable aqueous batteries with dilute electrolytes are recommended, based on the scientific discovery presented in this work.
(Less)
- author
- Zhang, Leiting
; Hou, Xu
LU
; Edström, Kristina
and Berg, Erik J.
- publishing date
- 2022-12
- type
- Contribution to journal
- publication status
- published
- keywords
- aqueous lithium-ion batteries, interfaces, layered compounds, mass spectrometry, water splitting
- in
- Batteries and Supercaps
- volume
- 5
- issue
- 12
- article number
- e202200336
- publisher
- Wiley-Blackwell
- external identifiers
-
- scopus:85139519217
- ISSN
- 2566-6223
- DOI
- 10.1002/batt.202200336
- language
- English
- LU publication?
- no
- additional info
- Publisher Copyright: © 2022 The Authors. Batteries & Supercaps published by Wiley-VCH GmbH.
- id
- 0017cddb-45c5-4406-a0bd-cd1d2389deda
- date added to LUP
- 2025-12-05 22:32:29
- date last changed
- 2025-12-11 14:38:45
@article{0017cddb-45c5-4406-a0bd-cd1d2389deda,
abstract = {{<p>Aqueous rechargeable batteries are appealing alternatives for large-scale energy storage. Reversible cycling of high-energy aqueous batteries has been showcased using highly concentrated aqueous electrolytes, which lead to a significantly suppressed water activity and formation of a stable solid-electrolyte interphase (SEI). However, the high salt concentration inevitably raises the cost and compromises the environmental sustainability. Herein, we use layered TiS<sub>2</sub> as a model anode to explore the feasibility of cycling aqueous cells in dilute electrolytes. By coupling three-electrode cycling data with online electrochemical mass spectrometry measurements, we depict the potential-dependent gas evolution from the cell in the absence of a stable SEI. We offer a comprehensive mechanistic understanding of the complex interfacial chemistry in dilute electrolytes, taking into account material reactivity and interfacial compatibility. Design strategies and research directions of layered-type electrodes for sustainable aqueous batteries with dilute electrolytes are recommended, based on the scientific discovery presented in this work.</p>}},
author = {{Zhang, Leiting and Hou, Xu and Edström, Kristina and Berg, Erik J.}},
issn = {{2566-6223}},
keywords = {{aqueous lithium-ion batteries; interfaces; layered compounds; mass spectrometry; water splitting}},
language = {{eng}},
number = {{12}},
publisher = {{Wiley-Blackwell}},
series = {{Batteries and Supercaps}},
title = {{Reactivity of TiS<sub>2</sub> Anode towards Electrolytes in Aqueous Lithium-Ion Batteries}},
url = {{http://dx.doi.org/10.1002/batt.202200336}},
doi = {{10.1002/batt.202200336}},
volume = {{5}},
year = {{2022}},
}