Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)
(2004) In Journal of Chemical Physics 120(19). p.8973-8978- Abstract
- The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/279757
- author
- Sprengers, JP ; Johansson, Allan LU ; Ubachs, W ; L'Huillier, Anne LU ; Wahlström, Claes-Göran LU ; Lang, R ; Lewis, BR and Gibson, ST
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 120
- issue
- 19
- pages
- 8973 - 8978
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000221146400010
- scopus:2942568207
- ISSN
- 0021-9606
- DOI
- 10.1063/1.1704640
- language
- English
- LU publication?
- yes
- id
- 0624aa6e-64a1-40e8-9dd0-847c00758f5c (old id 279757)
- date added to LUP
- 2016-04-01 12:02:12
- date last changed
- 2022-01-26 21:50:47
@article{0624aa6e-64a1-40e8-9dd0-847c00758f5c, abstract = {{The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.}}, author = {{Sprengers, JP and Johansson, Allan and Ubachs, W and L'Huillier, Anne and Wahlström, Claes-Göran and Lang, R and Lewis, BR and Gibson, ST}}, issn = {{0021-9606}}, language = {{eng}}, number = {{19}}, pages = {{8973--8978}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)}}, url = {{https://lup.lub.lu.se/search/files/2753335/2370782.pdf}}, doi = {{10.1063/1.1704640}}, volume = {{120}}, year = {{2004}}, }