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Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)

Sprengers, JP ; Johansson, Allan LU ; Ubachs, W ; L'Huillier, Anne LU orcid ; Wahlström, Claes-Göran LU ; Lang, R ; Lewis, BR and Gibson, ST (2004) In Journal of Chemical Physics 120(19). p.8973-8978
Abstract
The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.
Please use this url to cite or link to this publication:
author
; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
120
issue
19
pages
8973 - 8978
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000221146400010
  • scopus:2942568207
ISSN
0021-9606
DOI
10.1063/1.1704640
language
English
LU publication?
yes
id
0624aa6e-64a1-40e8-9dd0-847c00758f5c (old id 279757)
date added to LUP
2016-04-01 12:02:12
date last changed
2022-01-26 21:50:47
@article{0624aa6e-64a1-40e8-9dd0-847c00758f5c,
  abstract     = {{The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.}},
  author       = {{Sprengers, JP and Johansson, Allan and Ubachs, W and L'Huillier, Anne and Wahlström, Claes-Göran and Lang, R and Lewis, BR and Gibson, ST}},
  issn         = {{0021-9606}},
  language     = {{eng}},
  number       = {{19}},
  pages        = {{8973--8978}},
  publisher    = {{American Institute of Physics (AIP)}},
  series       = {{Journal of Chemical Physics}},
  title        = {{Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)}},
  url          = {{https://lup.lub.lu.se/search/files/2753335/2370782.pdf}},
  doi          = {{10.1063/1.1704640}},
  volume       = {{120}},
  year         = {{2004}},
}