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A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity

Neniškis, Algirdas ; Račkauskaitė, Dovilė ; Shi, Qixun LU ; Robertson, Aiden J. ; Marsh, Andrew ; Ulčinas, Artūras ; Valiokas, Ramūnas ; Brown, Steven P. ; Wärnmark, Kenneth LU and Orentas, Edvinas (2018) In Chemistry - A European Journal 24(53). p.14028-14033
Abstract

A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.

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author
; ; ; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
fullerenes, hydrogen-bond, molecular tubes, self-assembly, solid-state NMR
in
Chemistry - A European Journal
volume
24
issue
53
pages
6 pages
publisher
Wiley-VCH Verlag
external identifiers
  • pmid:30070741
  • scopus:85053461363
ISSN
0947-6539
DOI
10.1002/chem.201803701
language
English
LU publication?
yes
id
0b7145da-470e-497f-9b8d-0c6f617aa049
date added to LUP
2018-10-11 07:21:58
date last changed
2020-10-20 02:59:45
@article{0b7145da-470e-497f-9b8d-0c6f617aa049,
  abstract     = {<p>A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by <sup>1</sup>H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.</p>},
  author       = {Neniškis, Algirdas and Račkauskaitė, Dovilė and Shi, Qixun and Robertson, Aiden J. and Marsh, Andrew and Ulčinas, Artūras and Valiokas, Ramūnas and Brown, Steven P. and Wärnmark, Kenneth and Orentas, Edvinas},
  issn         = {0947-6539},
  language     = {eng},
  month        = {09},
  number       = {53},
  pages        = {14028--14033},
  publisher    = {Wiley-VCH Verlag},
  series       = {Chemistry - A European Journal},
  title        = {A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity},
  url          = {http://dx.doi.org/10.1002/chem.201803701},
  doi          = {10.1002/chem.201803701},
  volume       = {24},
  year         = {2018},
}