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Autoionisation of super excited states in N2 to the N2+ B state

Álvarez Ruiz, Jesús; Coreno, Marcelo; Erman, Peter; Kivimäki, Antti; Melero García, Emilio; Prince, Kevin; de Simone, M; Rachlew, Elisabeth; Richter, Robert and Rius i Riu, Jaume LU , et al. (2003) In Chemical Physics Letters 372(1-2). p.139-146
Abstract
Vibrationally resolved N2+ (B–X) (1–2) and (0–1) emission bands were recorded after photoexcitation of N2 in the 20–46 eV energy range. The branching ratio between these transitions reveals strong non-Franck–Condon effects. Ab initio calculations using a configuration interaction method based on Kohn–Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.
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publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Physics Letters
volume
372
issue
1-2
pages
139 - 146
publisher
Elsevier
external identifiers
  • scopus:0037461239
ISSN
0009-2614
DOI
10.1016/S0009-2614(03)00380-4
language
English
LU publication?
no
id
cb02cecc-abaa-492a-a17c-63825213aad2 (old id 1029556)
date added to LUP
2008-02-21 10:10:33
date last changed
2017-03-19 04:20:23
@article{cb02cecc-abaa-492a-a17c-63825213aad2,
  abstract     = {Vibrationally resolved N2+ (B–X) (1–2) and (0–1) emission bands were recorded after photoexcitation of N2 in the 20–46 eV energy range. The branching ratio between these transitions reveals strong non-Franck–Condon effects. Ab initio calculations using a configuration interaction method based on Kohn–Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.},
  author       = {Álvarez Ruiz, Jesús and Coreno, Marcelo and Erman, Peter and Kivimäki, Antti and Melero García, Emilio and Prince, Kevin and de Simone, M and Rachlew, Elisabeth and Richter, Robert and Rius i Riu, Jaume and Veseth, Leif},
  issn         = {0009-2614},
  language     = {eng},
  number       = {1-2},
  pages        = {139--146},
  publisher    = {Elsevier},
  series       = {Chemical Physics Letters},
  title        = {Autoionisation of super excited states in N2 to the N2+ B state},
  url          = {http://dx.doi.org/10.1016/S0009-2614(03)00380-4},
  volume       = {372},
  year         = {2003},
}