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Tetrakis(dimethyl sulfide)palladium(II) bis(tetrafluoroborate) and tetrakis(1,4-oxathiane-kappaS)palladium(II) bis(tetrafluoroborate).

Johansson, Maria LU and Oskarsson, Åke LU (2002) In Acta Crystallographica. Section C: Crystal Structure Communications 58(Pt 2). p.102-104
Abstract
Tetrakis(dimethyl sulfide)palladium(II) bis(tetrafluoroborate), [Pd(C(2)H(6)S)(4)](BF(4))(2), (I), and tetrakis(1,4-oxathiane-kappaS)palladium(II) bis(tetrafluoroborate), [Pd(C(4)H(8)OS)(4)](BF(4))(2), (II), both crystallize as mononuclear square-planar complexes with tetrafluoroborate as the counter-ions. The Pd atom accepts four S-donor atoms and is positioned at an inversion centre in both compounds. The two unique S atoms in the dimethyl sulfide complex, (I), are disordered. The Pd---S distances are in the range 2.3338(12)--2.3375(12)A in (I), and the corresponding distances in the thioxane complex, (II), are 2.3293(17) and 2.3406(17)A. The anions in both compounds interact weakly with the Pd atom.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
58
issue
Pt 2
pages
102 - 104
publisher
International Union of Crystallography
external identifiers
  • wos:000173796300015
  • pmid:11828094
  • scopus:0036486897
ISSN
0108-2701
DOI
10.1107/S0108270101019357
language
English
LU publication?
yes
id
f8ef8e02-95e5-4512-a339-c564de845a3b (old id 106175)
date added to LUP
2007-07-09 13:52:14
date last changed
2017-01-01 07:00:07
@article{f8ef8e02-95e5-4512-a339-c564de845a3b,
  abstract     = {Tetrakis(dimethyl sulfide)palladium(II) bis(tetrafluoroborate), [Pd(C(2)H(6)S)(4)](BF(4))(2), (I), and tetrakis(1,4-oxathiane-kappaS)palladium(II) bis(tetrafluoroborate), [Pd(C(4)H(8)OS)(4)](BF(4))(2), (II), both crystallize as mononuclear square-planar complexes with tetrafluoroborate as the counter-ions. The Pd atom accepts four S-donor atoms and is positioned at an inversion centre in both compounds. The two unique S atoms in the dimethyl sulfide complex, (I), are disordered. The Pd---S distances are in the range 2.3338(12)--2.3375(12)A in (I), and the corresponding distances in the thioxane complex, (II), are 2.3293(17) and 2.3406(17)A. The anions in both compounds interact weakly with the Pd atom.},
  author       = {Johansson, Maria and Oskarsson, Åke},
  issn         = {0108-2701},
  language     = {eng},
  number       = {Pt 2},
  pages        = {102--104},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica. Section C: Crystal Structure Communications},
  title        = {Tetrakis(dimethyl sulfide)palladium(II) bis(tetrafluoroborate) and tetrakis(1,4-oxathiane-kappaS)palladium(II) bis(tetrafluoroborate).},
  url          = {http://dx.doi.org/10.1107/S0108270101019357},
  volume       = {58},
  year         = {2002},
}