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Molecularly imprinted polymer coatings for open-tubular capillary electrochromatography prepared by surface initiation.

Schweitz, Leif LU (2002) In Analytical Chemistry 74(5). p.1192-1192
Abstract
Molecularly imprinted polymer coatings were synthesized in fused-silica capillary columns by the use of a surface-coupled radical initiator. The coatings were prepared using either toluene, dichloromethane, or acetonitrile in the prepolymerization mixtures and were 0.15-2 microm thick as determined by scanning electron microscopy. Solvent-dependent differences in appearance were observed. All the molecularly imprinted polymer-based open-tubular capillary columns were able to separate the enantiomers of propranolol by means of electrochromatography. Electrochromatographic performance was found to be dependent on the type of solvent used during the synthesis.
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Electrophoresis, Capillary : instrumentation, Microscopy, Electron, Polymers, Propranolol : chemistry, Propranolol : isolation & purification, Support, Non-U.S. Gov't
in
Analytical Chemistry
volume
74
issue
5
pages
1192 - 1192
publisher
The American Chemical Society
external identifiers
  • wos:000174187900042
  • pmid:11924984
  • scopus:0036500293
ISSN
1520-6882
DOI
10.1021/ac0156520
language
English
LU publication?
yes
id
473a751b-a998-4a2d-86ac-56154bcaa836 (old id 107311)
date added to LUP
2007-06-27 15:29:53
date last changed
2017-07-02 03:35:23
@article{473a751b-a998-4a2d-86ac-56154bcaa836,
  abstract     = {Molecularly imprinted polymer coatings were synthesized in fused-silica capillary columns by the use of a surface-coupled radical initiator. The coatings were prepared using either toluene, dichloromethane, or acetonitrile in the prepolymerization mixtures and were 0.15-2 microm thick as determined by scanning electron microscopy. Solvent-dependent differences in appearance were observed. All the molecularly imprinted polymer-based open-tubular capillary columns were able to separate the enantiomers of propranolol by means of electrochromatography. Electrochromatographic performance was found to be dependent on the type of solvent used during the synthesis.},
  author       = {Schweitz, Leif},
  issn         = {1520-6882},
  keyword      = {Electrophoresis,Capillary : instrumentation,Microscopy,Electron,Polymers,Propranolol : chemistry,Propranolol : isolation & purification,Support,Non-U.S. Gov't},
  language     = {eng},
  number       = {5},
  pages        = {1192--1192},
  publisher    = {The American Chemical Society},
  series       = {Analytical Chemistry},
  title        = {Molecularly imprinted polymer coatings for open-tubular capillary electrochromatography prepared by surface initiation.},
  url          = {http://dx.doi.org/10.1021/ac0156520},
  volume       = {74},
  year         = {2002},
}