Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Microporous La-Metal-Organic Framework (MOF) with Large Surface Area

Pal, Souvik ; Bhunia, Asamanjoy ; Jana, Partha LU ; Dey, Subarna ; Moellmer, Jens ; Janiak, Christoph and Nayek, Hari Pada (2015) In Chemistry: A European Journal 21(7). p.2789-2792
Abstract
A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.
Please use this url to cite or link to this publication:
author
; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
adsorption, chemical stability, lanthanides, metal-organic frameworks, structure elucidation
in
Chemistry: A European Journal
volume
21
issue
7
pages
2789 - 2792
publisher
Wiley-Blackwell
external identifiers
  • wos:000349384300011
  • pmid:25521611
  • scopus:84921939630
ISSN
1521-3765
DOI
10.1002/chem.201405168
language
English
LU publication?
yes
id
11827172-b70f-4c03-8769-0585c5916225 (old id 5175894)
date added to LUP
2016-04-01 14:31:42
date last changed
2022-08-07 06:00:47
@article{11827172-b70f-4c03-8769-0585c5916225,
  abstract     = {{A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.}},
  author       = {{Pal, Souvik and Bhunia, Asamanjoy and Jana, Partha and Dey, Subarna and Moellmer, Jens and Janiak, Christoph and Nayek, Hari Pada}},
  issn         = {{1521-3765}},
  keywords     = {{adsorption; chemical stability; lanthanides; metal-organic frameworks; structure elucidation}},
  language     = {{eng}},
  number       = {{7}},
  pages        = {{2789--2792}},
  publisher    = {{Wiley-Blackwell}},
  series       = {{Chemistry: A European Journal}},
  title        = {{Microporous La-Metal-Organic Framework (MOF) with Large Surface Area}},
  url          = {{http://dx.doi.org/10.1002/chem.201405168}},
  doi          = {{10.1002/chem.201405168}},
  volume       = {{21}},
  year         = {{2015}},
}