Re4As6S3, a thio-spinel-related cluster system.
(2003) In Journal of Solid State Chemistry 172(2). p.446-450- Abstract
- We have synthesized a new compound with formula Re4As6S3 and characterized its crystal structure by Rietveld powder diffraction methods. Re4As6S3 crystallizes in an face-centered cubic unit cell, space group F (4) over bar 3m (no. 216), with lattice constant a = 9.8608(1) Angstrom and Z = 4. The rhenium atoms form tetrahedral clusters linked via tetrahedral arsenic clusters to produce an NaCl-type arrangement. The oxidation state of rhenium is IV and the number of electrons shared by the rhenium atoms in the cluster is 12. The structure is based on an ordered defect thio-spinel A((1-x))B(2)X(4) where the B-type atoms form tetrahedral clusters. (C) 2003 Elsevier Science (USA). All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/120947
- author
- Besnard, Céline LU ; Svensson, C ; Ståhl, K and Siegrist, Theo LU
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- arsenic clusters, rhenium compounds, tetrahedral clusters, thio-spinels
- in
- Journal of Solid State Chemistry
- volume
- 172
- issue
- 2
- pages
- 446 - 450
- publisher
- Elsevier
- external identifiers
-
- wos:000183360200025
- scopus:0344496295
- ISSN
- 0022-4596
- DOI
- 10.1016/S0022-4596(03)00032-X
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 19a486e9-4bd0-4460-83c9-1245b8c903e3 (old id 120947)
- date added to LUP
- 2016-04-01 16:21:50
- date last changed
- 2022-01-28 19:12:14
@article{19a486e9-4bd0-4460-83c9-1245b8c903e3, abstract = {{We have synthesized a new compound with formula Re4As6S3 and characterized its crystal structure by Rietveld powder diffraction methods. Re4As6S3 crystallizes in an face-centered cubic unit cell, space group F (4) over bar 3m (no. 216), with lattice constant a = 9.8608(1) Angstrom and Z = 4. The rhenium atoms form tetrahedral clusters linked via tetrahedral arsenic clusters to produce an NaCl-type arrangement. The oxidation state of rhenium is IV and the number of electrons shared by the rhenium atoms in the cluster is 12. The structure is based on an ordered defect thio-spinel A((1-x))B(2)X(4) where the B-type atoms form tetrahedral clusters. (C) 2003 Elsevier Science (USA). All rights reserved.}}, author = {{Besnard, Céline and Svensson, C and Ståhl, K and Siegrist, Theo}}, issn = {{0022-4596}}, keywords = {{arsenic clusters; rhenium compounds; tetrahedral clusters; thio-spinels}}, language = {{eng}}, number = {{2}}, pages = {{446--450}}, publisher = {{Elsevier}}, series = {{Journal of Solid State Chemistry}}, title = {{Re4As6S3, a thio-spinel-related cluster system.}}, url = {{http://dx.doi.org/10.1016/S0022-4596(03)00032-X}}, doi = {{10.1016/S0022-4596(03)00032-X}}, volume = {{172}}, year = {{2003}}, }