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Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

Arunachalampillai, Athimoolam; Johnson, Magnus LU and Wendt, Ola LU (2008) In Organometallics 27(17). p.4541-4543
Abstract
Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
27
issue
17
pages
4541 - 4543
publisher
The American Chemical Society
external identifiers
  • wos:000258898300033
  • scopus:52649165620
ISSN
1520-6041
DOI
10.1021/om800444g
language
English
LU publication?
yes
id
bcfd6ba8-ca72-40cf-987d-5b25998803cd (old id 1247192)
date added to LUP
2008-11-11 09:06:23
date last changed
2017-01-01 05:14:31
@article{bcfd6ba8-ca72-40cf-987d-5b25998803cd,
  abstract     = {Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.},
  author       = {Arunachalampillai, Athimoolam and Johnson, Magnus and Wendt, Ola},
  issn         = {1520-6041},
  language     = {eng},
  number       = {17},
  pages        = {4541--4543},
  publisher    = {The American Chemical Society},
  series       = {Organometallics},
  title        = {Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands},
  url          = {http://dx.doi.org/10.1021/om800444g},
  volume       = {27},
  year         = {2008},
}