Reaction mechanism of the oxidation of HCl over RuO2(110)
(2008) In Journal of Physical Chemistry C 112(27). p.9966-9969- Abstract
- High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1254704
- author
- Zweidinger, S. ; Crihan, D. ; Knapp, M. ; Hofmann, J. P. ; Seitsonen, A. P. ; Weststrate, C J ; Lundgren, Edvin LU ; Andersen, Jesper N LU and Over, H.
- organization
- publishing date
- 2008
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physical Chemistry C
- volume
- 112
- issue
- 27
- pages
- 9966 - 9969
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000257335300002
- scopus:49249112102
- ISSN
- 1932-7447
- DOI
- 10.1021/jp803346q
- language
- English
- LU publication?
- yes
- id
- d82cbc6e-8aae-4615-ac25-1786b26e3173 (old id 1254704)
- date added to LUP
- 2016-04-01 11:58:00
- date last changed
- 2022-02-03 07:41:16
@article{d82cbc6e-8aae-4615-ac25-1786b26e3173, abstract = {{High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.}}, author = {{Zweidinger, S. and Crihan, D. and Knapp, M. and Hofmann, J. P. and Seitsonen, A. P. and Weststrate, C J and Lundgren, Edvin and Andersen, Jesper N and Over, H.}}, issn = {{1932-7447}}, language = {{eng}}, number = {{27}}, pages = {{9966--9969}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Journal of Physical Chemistry C}}, title = {{Reaction mechanism of the oxidation of HCl over RuO2(110)}}, url = {{http://dx.doi.org/10.1021/jp803346q}}, doi = {{10.1021/jp803346q}}, volume = {{112}}, year = {{2008}}, }