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Reaction mechanism of the oxidation of HCl over RuO2(110)

Zweidinger, S.; Crihan, D.; Knapp, M.; Hofmann, J. P.; Seitsonen, A. P.; Weststrate, C J; Lundgren, Edvin LU ; Andersen, Jesper N LU and Over, H. (2008) In Journal of Physical Chemistry C 112(27). p.9966-9969
Abstract
High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Physical Chemistry C
volume
112
issue
27
pages
9966 - 9969
publisher
The American Chemical Society
external identifiers
  • wos:000257335300002
  • scopus:49249112102
ISSN
1932-7447
DOI
10.1021/jp803346q
language
English
LU publication?
yes
id
d82cbc6e-8aae-4615-ac25-1786b26e3173 (old id 1254704)
date added to LUP
2008-10-29 15:55:16
date last changed
2017-10-22 03:42:21
@article{d82cbc6e-8aae-4615-ac25-1786b26e3173,
  abstract     = {High-resolution core-level shift spectroscopy and temperature-programmed reaction experiments together with density functional theory calculations reveal that the oxidation of HCl with oxygen producing Cl-2 and water proceeds on the chlorine-stabilized RuO2(110)surface via a one-dimensional Langmuir-Hinshelwood mechanism. The recombination of two adjacent chlorine atoms on the catalyst's surface constitutes the rate-determining step in this novel Deacon-like process.},
  author       = {Zweidinger, S. and Crihan, D. and Knapp, M. and Hofmann, J. P. and Seitsonen, A. P. and Weststrate, C J and Lundgren, Edvin and Andersen, Jesper N and Over, H.},
  issn         = {1932-7447},
  language     = {eng},
  number       = {27},
  pages        = {9966--9969},
  publisher    = {The American Chemical Society},
  series       = {Journal of Physical Chemistry C},
  title        = {Reaction mechanism of the oxidation of HCl over RuO2(110)},
  url          = {http://dx.doi.org/10.1021/jp803346q},
  volume       = {112},
  year         = {2008},
}