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Lab-scale versus industrial-scale thermal runaway tests for lithium-ion battery cells

Willstrand, Ola ; Yang, Yang ; Andersson, Petra LU and Brandell, Daniel (2025) In Journal of Energy Storage 129.
Abstract

Lithium-ion battery safety is a topic of large importance, and testing is associated with large costs. Safety evaluation is therefore needed also at an early stage in cell design and development, in order to evaluate potential short-comings or to screen large platforms of materials and cells. Previous thermal runaway tests on lab-scale cells have, however, indicated differences in heat release and temperature increase as compared to commercial cells. On the other hand, these could also vary between different commercial cells due to differences in cell materials, size, format, and design. In this work, thermal runaway characteristics of industrial-scale cells are compared against each other as well as with lab-scale cells. Tests were... (More)

Lithium-ion battery safety is a topic of large importance, and testing is associated with large costs. Safety evaluation is therefore needed also at an early stage in cell design and development, in order to evaluate potential short-comings or to screen large platforms of materials and cells. Previous thermal runaway tests on lab-scale cells have, however, indicated differences in heat release and temperature increase as compared to commercial cells. On the other hand, these could also vary between different commercial cells due to differences in cell materials, size, format, and design. In this work, thermal runaway characteristics of industrial-scale cells are compared against each other as well as with lab-scale cells. Tests were performed on lab-scale coin cells and five different industrial-scale cells ranging from 5 to 157 Ah, covering different cell formats and materials. The coin cells were built using electrodes and separator extracted from one of the industrial-scale cells. The results show that the thermal runaway will be less violent and reach lower maximum temperatures using lab-scale cells, depending on the lower proportion of active materials as compared to inactive components. It is also shown that the ratio between cell capacity and heat capacity is a useful indicator for the comparability of thermal runaway scenarios. This ratio varies considerably for small cells, but not so much for different commercial cells. The data available suggests that a cell capacity of at least 1 Ah is needed to achieve a good comparison of the thermal runaway scenario with larger commercial cells.

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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Gas production, Heat production, Lab-scale cell, Li-ion battery, Thermal runaway
in
Journal of Energy Storage
volume
129
article number
117275
publisher
Elsevier
external identifiers
  • scopus:105006976098
ISSN
2352-1538
DOI
10.1016/j.est.2025.117275
language
English
LU publication?
yes
id
13195996-99b8-423f-8553-cfd0cfe93824
date added to LUP
2025-07-17 11:28:10
date last changed
2025-07-17 11:29:02
@article{13195996-99b8-423f-8553-cfd0cfe93824,
  abstract     = {{<p>Lithium-ion battery safety is a topic of large importance, and testing is associated with large costs. Safety evaluation is therefore needed also at an early stage in cell design and development, in order to evaluate potential short-comings or to screen large platforms of materials and cells. Previous thermal runaway tests on lab-scale cells have, however, indicated differences in heat release and temperature increase as compared to commercial cells. On the other hand, these could also vary between different commercial cells due to differences in cell materials, size, format, and design. In this work, thermal runaway characteristics of industrial-scale cells are compared against each other as well as with lab-scale cells. Tests were performed on lab-scale coin cells and five different industrial-scale cells ranging from 5 to 157 Ah, covering different cell formats and materials. The coin cells were built using electrodes and separator extracted from one of the industrial-scale cells. The results show that the thermal runaway will be less violent and reach lower maximum temperatures using lab-scale cells, depending on the lower proportion of active materials as compared to inactive components. It is also shown that the ratio between cell capacity and heat capacity is a useful indicator for the comparability of thermal runaway scenarios. This ratio varies considerably for small cells, but not so much for different commercial cells. The data available suggests that a cell capacity of at least 1 Ah is needed to achieve a good comparison of the thermal runaway scenario with larger commercial cells.</p>}},
  author       = {{Willstrand, Ola and Yang, Yang and Andersson, Petra and Brandell, Daniel}},
  issn         = {{2352-1538}},
  keywords     = {{Gas production; Heat production; Lab-scale cell; Li-ion battery; Thermal runaway}},
  language     = {{eng}},
  publisher    = {{Elsevier}},
  series       = {{Journal of Energy Storage}},
  title        = {{Lab-scale versus industrial-scale thermal runaway tests for lithium-ion battery cells}},
  url          = {{http://dx.doi.org/10.1016/j.est.2025.117275}},
  doi          = {{10.1016/j.est.2025.117275}},
  volume       = {{129}},
  year         = {{2025}},
}