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Direct heterogeneous electron transfer reactions of bilirubin oxidase at a spectrographic graphite electrode

Shleev, Sergey LU ; El Kasmi, A; Ruzgas, Tautgirdas LU and Gorton, Lo LU (2004) In Electrochemistry Communications 6(9). p.934-939
Abstract
Mediatorless (direct) electron transfer between Myrothecium verrucaria bilirubin oxidase and spectroscopic graphite electrode has been demonstrated. The electrochemical activity of the enzyme under aerobic and anaerobic conditions is clearly shown using cyclic voltammetry. It is concluded that the T1 site of the enzyme is the first electron acceptor, both in solution (homogenous case) and when the bilirubin oxidase is adsorbed on the surface of the graphite electrode (heterogeneous case). (C) 2004 Elsevier B.V. All rights reserved.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Electrochemistry Communications
volume
6
issue
9
pages
934 - 939
publisher
Elsevier
external identifiers
  • wos:000223496800012
  • scopus:4143122049
ISSN
1388-2481
DOI
10.1016/j.elecom.2004.07.008
language
English
LU publication?
yes
id
056838a9-9d4b-4ace-a5d1-09417ced3eec (old id 138416)
date added to LUP
2007-06-27 15:46:14
date last changed
2017-10-01 03:54:40
@article{056838a9-9d4b-4ace-a5d1-09417ced3eec,
  abstract     = {Mediatorless (direct) electron transfer between Myrothecium verrucaria bilirubin oxidase and spectroscopic graphite electrode has been demonstrated. The electrochemical activity of the enzyme under aerobic and anaerobic conditions is clearly shown using cyclic voltammetry. It is concluded that the T1 site of the enzyme is the first electron acceptor, both in solution (homogenous case) and when the bilirubin oxidase is adsorbed on the surface of the graphite electrode (heterogeneous case). (C) 2004 Elsevier B.V. All rights reserved.},
  author       = {Shleev, Sergey and El Kasmi, A and Ruzgas, Tautgirdas and Gorton, Lo},
  issn         = {1388-2481},
  language     = {eng},
  number       = {9},
  pages        = {934--939},
  publisher    = {Elsevier},
  series       = {Electrochemistry Communications},
  title        = {Direct heterogeneous electron transfer reactions of bilirubin oxidase at a spectrographic graphite electrode},
  url          = {http://dx.doi.org/10.1016/j.elecom.2004.07.008},
  volume       = {6},
  year         = {2004},
}