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Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes

Pushkar, Julia and Wendt, Ola LU (2004) In Inorganica Chimica Acta 357(4). p.1295-1298
Abstract
Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium complexes, Crystal structures, Carbon dioxide, Carbonate complexes
in
Inorganica Chimica Acta
volume
357
issue
4
pages
1295 - 1298
publisher
Elsevier
external identifiers
  • wos:000220241400046
  • scopus:1542316385
ISSN
0020-1693
DOI
10.1016/j.ica.2003.10.027
language
English
LU publication?
yes
id
cf2b51a8-4e7d-4251-89ee-323754e46951 (old id 141259)
date added to LUP
2007-07-10 13:38:37
date last changed
2017-12-10 04:40:16
@article{cf2b51a8-4e7d-4251-89ee-323754e46951,
  abstract     = {Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.},
  author       = {Pushkar, Julia and Wendt, Ola},
  issn         = {0020-1693},
  keyword      = {Palladium complexes,Crystal structures,Carbon dioxide,Carbonate complexes},
  language     = {eng},
  number       = {4},
  pages        = {1295--1298},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes},
  url          = {http://dx.doi.org/10.1016/j.ica.2003.10.027},
  volume       = {357},
  year         = {2004},
}