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Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes

Pushkar, Julia and Wendt, Ola LU (2004) In Inorganica Chimica Acta 357(4). p.1295-1298
Abstract
Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium complexes, Crystal structures, Carbon dioxide, Carbonate complexes
in
Inorganica Chimica Acta
volume
357
issue
4
pages
1295 - 1298
publisher
Elsevier
external identifiers
  • wos:000220241400046
  • scopus:1542316385
ISSN
0020-1693
DOI
10.1016/j.ica.2003.10.027
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
cf2b51a8-4e7d-4251-89ee-323754e46951 (old id 141259)
date added to LUP
2016-04-01 17:13:28
date last changed
2022-03-23 00:11:24
@article{cf2b51a8-4e7d-4251-89ee-323754e46951,
  abstract     = {{Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.}},
  author       = {{Pushkar, Julia and Wendt, Ola}},
  issn         = {{0020-1693}},
  keywords     = {{Palladium complexes; Crystal structures; Carbon dioxide; Carbonate complexes}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{1295--1298}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2003.10.027}},
  doi          = {{10.1016/j.ica.2003.10.027}},
  volume       = {{357}},
  year         = {{2004}},
}