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Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Thapper, Anders; Sparr, Emma LU ; Johnson, Brian F G; Lewis, Jack; Raithby, Paul R and Nordlander, Ebbe LU (2004) In Inorganic Chemistry Communications 7(3). p.443-446
Abstract
The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Cluster, Hemilabile ligand, Allylphosphine
in
Inorganic Chemistry Communications
volume
7
issue
3
pages
443 - 446
publisher
Elsevier
external identifiers
  • wos:000189229800037
  • scopus:1242351272
ISSN
1879-0259
DOI
10.1016/j.inoche.2003.12.032
language
English
LU publication?
yes
id
fac8d727-8ca7-4c77-8916-3cfd8477fcbe (old id 141569)
date added to LUP
2007-07-09 14:17:27
date last changed
2017-01-01 04:33:17
@article{fac8d727-8ca7-4c77-8916-3cfd8477fcbe,
  abstract     = {The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].},
  author       = {Thapper, Anders and Sparr, Emma and Johnson, Brian F G and Lewis, Jack and Raithby, Paul R and Nordlander, Ebbe},
  issn         = {1879-0259},
  keyword      = {Cluster,Hemilabile ligand,Allylphosphine},
  language     = {eng},
  number       = {3},
  pages        = {443--446},
  publisher    = {Elsevier},
  series       = {Inorganic Chemistry Communications},
  title        = {Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster},
  url          = {http://dx.doi.org/10.1016/j.inoche.2003.12.032},
  volume       = {7},
  year         = {2004},
}