Water-olefin complexes. : A matrix isolation study
(1986) In Journal of Physical Chemistry 90(21). p.4982-4987- Abstract
The infrared spectra of the H2O, HDO, and D2O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.
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https://lup.lub.lu.se/record/1415dec0-5985-4aae-a6db-1b6fd5c0a8ed
- author
- Engdahl, Anders LU and Nelander, Bengt LU
- organization
- publishing date
- 1986
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physical Chemistry
- volume
- 90
- issue
- 21
- pages
- 6 pages
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:0001424658
- ISSN
- 0022-3654
- DOI
- 10.1021/j100412a023
- language
- English
- LU publication?
- yes
- additional info
- Copyright: Copyright 2017 Elsevier B.V., All rights reserved.
- id
- 1415dec0-5985-4aae-a6db-1b6fd5c0a8ed
- date added to LUP
- 2021-03-29 15:21:23
- date last changed
- 2021-07-11 05:20:45
@article{1415dec0-5985-4aae-a6db-1b6fd5c0a8ed, abstract = {{<p>The infrared spectra of the H<sub>2</sub>O, HDO, and D<sub>2</sub>O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.</p>}}, author = {{Engdahl, Anders and Nelander, Bengt}}, issn = {{0022-3654}}, language = {{eng}}, number = {{21}}, pages = {{4982--4987}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Journal of Physical Chemistry}}, title = {{Water-olefin complexes. : A matrix isolation study}}, url = {{http://dx.doi.org/10.1021/j100412a023}}, doi = {{10.1021/j100412a023}}, volume = {{90}}, year = {{1986}}, }