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Water-olefin complexes. : A matrix isolation study

Engdahl, Anders LU and Nelander, Bengt LU (1986) In Journal of Physical Chemistry 90(21). p.4982-4987
Abstract

The infrared spectra of the H2O, HDO, and D2O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.

Please use this url to cite or link to this publication:
author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Physical Chemistry
volume
90
issue
21
pages
6 pages
publisher
The American Chemical Society (ACS)
external identifiers
  • scopus:0001424658
ISSN
0022-3654
DOI
10.1021/j100412a023
language
English
LU publication?
yes
additional info
Copyright: Copyright 2017 Elsevier B.V., All rights reserved.
id
1415dec0-5985-4aae-a6db-1b6fd5c0a8ed
date added to LUP
2021-03-29 15:21:23
date last changed
2021-07-11 05:20:45
@article{1415dec0-5985-4aae-a6db-1b6fd5c0a8ed,
  abstract     = {{<p>The infrared spectra of the H<sub>2</sub>O, HDO, and D<sub>2</sub>O complexes with ethylene, propene, cis-2-butene, trans-2-butene, 2-methylpropene, 2-methyl-2-butene, 2,3-dimethyl-2-butene, 1,3-butadiene, benzene, and naphthalene have been recorded at temperatures from 11 to 20 K. Interaction energies have been estimated. HDO prefers to form a deuterium bond to the unsaturated molecule; however, small amounts of the hydrogen-bonded forms are present in thermal equilibrium with the deuterium-bonded forms. The energy difference between the hydrogen-bonded and deuterium-bonded forms has been estimated for most of the complexes.</p>}},
  author       = {{Engdahl, Anders and Nelander, Bengt}},
  issn         = {{0022-3654}},
  language     = {{eng}},
  number       = {{21}},
  pages        = {{4982--4987}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Journal of Physical Chemistry}},
  title        = {{Water-olefin complexes. : A matrix isolation study}},
  url          = {{http://dx.doi.org/10.1021/j100412a023}},
  doi          = {{10.1021/j100412a023}},
  volume       = {{90}},
  year         = {{1986}},
}