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Assignment of the L2,3VV normal Auger decay spectrum of Cl-2 by ab initio calculations

Travnikova, Oksana; Fink, Reinhold F.; Kivimaki, Antti; Céolin, Denis LU ; Bao, Zhuo and Piancastelli, Maria Novella (2009) In Chemical Physics Letters 474(1-3). p.67-73
Abstract
Auger decay processes of the Cl 2p ionized states have been studied in Cl-2 by means of high- resolution electron spectroscopy and ab initio calculations. This led to reassignment of the normal L2,3VV Auger decay spectrum of Cl2. The reliability of this assignment is strongly supported by an independent measurement of the L2; 3VV Auger electron spectrum of Cl2 which has been obtained after selective Cl 2p(3/2)(-1) photoionization of the chlorine molecule. Partial Auger transition rates for the three nongenerate spin-orbit and molecular- field- split 2p(-1) states - 2p(3/2,3/2)(-1) ((2)Pi(3/2)), 2p(3/2,1/2)(-1)((2)Sigma(+)(1/2)) and 2p(1/2,1/2)(-1)((2)Pi(1/2)) - show differences similar to the ones reported in previous works for HCl. (C)... (More)
Auger decay processes of the Cl 2p ionized states have been studied in Cl-2 by means of high- resolution electron spectroscopy and ab initio calculations. This led to reassignment of the normal L2,3VV Auger decay spectrum of Cl2. The reliability of this assignment is strongly supported by an independent measurement of the L2; 3VV Auger electron spectrum of Cl2 which has been obtained after selective Cl 2p(3/2)(-1) photoionization of the chlorine molecule. Partial Auger transition rates for the three nongenerate spin-orbit and molecular- field- split 2p(-1) states - 2p(3/2,3/2)(-1) ((2)Pi(3/2)), 2p(3/2,1/2)(-1)((2)Sigma(+)(1/2)) and 2p(1/2,1/2)(-1)((2)Pi(1/2)) - show differences similar to the ones reported in previous works for HCl. (C) 2009 Elsevier B. V. All rights reserved. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Physics Letters
volume
474
issue
1-3
pages
67 - 73
publisher
Elsevier
external identifiers
  • wos:000266115800014
  • scopus:65549127654
ISSN
0009-2614
DOI
10.1016/j.cplett.2009.04.058
language
English
LU publication?
yes
id
37f31695-7ace-4a76-895c-5132a05f0cad (old id 1426226)
date added to LUP
2009-06-26 13:33:02
date last changed
2017-01-01 05:39:34
@article{37f31695-7ace-4a76-895c-5132a05f0cad,
  abstract     = {Auger decay processes of the Cl 2p ionized states have been studied in Cl-2 by means of high- resolution electron spectroscopy and ab initio calculations. This led to reassignment of the normal L2,3VV Auger decay spectrum of Cl2. The reliability of this assignment is strongly supported by an independent measurement of the L2; 3VV Auger electron spectrum of Cl2 which has been obtained after selective Cl 2p(3/2)(-1) photoionization of the chlorine molecule. Partial Auger transition rates for the three nongenerate spin-orbit and molecular- field- split 2p(-1) states - 2p(3/2,3/2)(-1) ((2)Pi(3/2)), 2p(3/2,1/2)(-1)((2)Sigma(+)(1/2)) and 2p(1/2,1/2)(-1)((2)Pi(1/2)) - show differences similar to the ones reported in previous works for HCl. (C) 2009 Elsevier B. V. All rights reserved.},
  author       = {Travnikova, Oksana and Fink, Reinhold F. and Kivimaki, Antti and Céolin, Denis and Bao, Zhuo and Piancastelli, Maria Novella},
  issn         = {0009-2614},
  language     = {eng},
  number       = {1-3},
  pages        = {67--73},
  publisher    = {Elsevier},
  series       = {Chemical Physics Letters},
  title        = {Assignment of the L2,3VV normal Auger decay spectrum of Cl-2 by ab initio calculations},
  url          = {http://dx.doi.org/10.1016/j.cplett.2009.04.058},
  volume       = {474},
  year         = {2009},
}