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Dark excited states of carotenoids: Consensus and controversy

Polivka, Tomas LU and Sundström, Villy LU (2009) In Chemical Physics Letters 477(1-3). p.1-11
Abstract
Excited-state dynamics of carotenoids has attracted considerable recent interest, but it has also engendered a number of controversial hypotheses. This review summarizes the knowledge gathered from various ultrafast time-resolved techniques addressing the two most discussed dark excited states (1B(u)(-) and S*). These two states have been subjects of numerous earlier studies, because while the 1B(u)(-) state was predicted by theory a long time ago but never clearly observed in experiment, the S* state is readily observed in transient absorption data, but no theoretical explanation of its origin has been available until recently. The major focus of this review is (1) the possible role of the 1B(u)(-) state in excited-state processes and (2)... (More)
Excited-state dynamics of carotenoids has attracted considerable recent interest, but it has also engendered a number of controversial hypotheses. This review summarizes the knowledge gathered from various ultrafast time-resolved techniques addressing the two most discussed dark excited states (1B(u)(-) and S*). These two states have been subjects of numerous earlier studies, because while the 1B(u)(-) state was predicted by theory a long time ago but never clearly observed in experiment, the S* state is readily observed in transient absorption data, but no theoretical explanation of its origin has been available until recently. The major focus of this review is (1) the possible role of the 1B(u)(-) state in excited-state processes and (2) the origin and mechanism of formation of the S* state in carotenoids. (c) 2009 Elsevier B. V. All rights reserved. (Less)
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publication status
published
subject
in
Chemical Physics Letters
volume
477
issue
1-3
pages
1 - 11
publisher
Elsevier
external identifiers
  • wos:000268329800001
  • scopus:67650715000
ISSN
0009-2614
DOI
10.1016/j.cplett.2009.06.011
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
b22a99f8-ce3c-45f9-8d15-9ba2ab53aa9a (old id 1460670)
date added to LUP
2016-04-01 14:33:13
date last changed
2021-08-11 01:58:53
@article{b22a99f8-ce3c-45f9-8d15-9ba2ab53aa9a,
  abstract     = {Excited-state dynamics of carotenoids has attracted considerable recent interest, but it has also engendered a number of controversial hypotheses. This review summarizes the knowledge gathered from various ultrafast time-resolved techniques addressing the two most discussed dark excited states (1B(u)(-) and S*). These two states have been subjects of numerous earlier studies, because while the 1B(u)(-) state was predicted by theory a long time ago but never clearly observed in experiment, the S* state is readily observed in transient absorption data, but no theoretical explanation of its origin has been available until recently. The major focus of this review is (1) the possible role of the 1B(u)(-) state in excited-state processes and (2) the origin and mechanism of formation of the S* state in carotenoids. (c) 2009 Elsevier B. V. All rights reserved.},
  author       = {Polivka, Tomas and Sundström, Villy},
  issn         = {0009-2614},
  language     = {eng},
  number       = {1-3},
  pages        = {1--11},
  publisher    = {Elsevier},
  series       = {Chemical Physics Letters},
  title        = {Dark excited states of carotenoids: Consensus and controversy},
  url          = {http://dx.doi.org/10.1016/j.cplett.2009.06.011},
  doi          = {10.1016/j.cplett.2009.06.011},
  volume       = {477},
  year         = {2009},
}