As UF3 Molecule with a Weak Triple Bond to Uranium
(2009) In Inorganic Chemistry 48(14). p.6594-6598- Abstract
- After reactions of uranium atoms with NF3 and PF3 to form the N UF3 and P UF3 molecules, the analogous reaction with AsF3 produced the novel terminal arsenide As UF3. This first molecule with a uranium-arsenic bond was identified from matrix infrared spectra through comparison with spectra of the uranium nitride and phosphide species, with spectra using other metals, and with frequencies computed by density functional and multiconfigurational wave function methods. The latter calculation describes a weak triple bond to uranium in the As UF3 molecule, which has slightly less bonding and more antibonding character than the weak triple bond in P UF3.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1461584
- author
- Andrews, Lester ; Wang, Xuefeng and Roos, Björn LU
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Inorganic Chemistry
- volume
- 48
- issue
- 14
- pages
- 6594 - 6598
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000268137900039
- scopus:67650538809
- pmid:19514741
- ISSN
- 1520-510X
- DOI
- 10.1021/ic9005696
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
- id
- 2742465a-2cae-497f-8cdb-07ec11616c3e (old id 1461584)
- date added to LUP
- 2016-04-01 11:42:00
- date last changed
- 2023-01-02 22:09:13
@article{2742465a-2cae-497f-8cdb-07ec11616c3e, abstract = {{After reactions of uranium atoms with NF3 and PF3 to form the N UF3 and P UF3 molecules, the analogous reaction with AsF3 produced the novel terminal arsenide As UF3. This first molecule with a uranium-arsenic bond was identified from matrix infrared spectra through comparison with spectra of the uranium nitride and phosphide species, with spectra using other metals, and with frequencies computed by density functional and multiconfigurational wave function methods. The latter calculation describes a weak triple bond to uranium in the As UF3 molecule, which has slightly less bonding and more antibonding character than the weak triple bond in P UF3.}}, author = {{Andrews, Lester and Wang, Xuefeng and Roos, Björn}}, issn = {{1520-510X}}, language = {{eng}}, number = {{14}}, pages = {{6594--6598}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Inorganic Chemistry}}, title = {{As UF3 Molecule with a Weak Triple Bond to Uranium}}, url = {{http://dx.doi.org/10.1021/ic9005696}}, doi = {{10.1021/ic9005696}}, volume = {{48}}, year = {{2009}}, }