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Efficient solution of the self-consistent field theory for block copolymer fluids displaying Schulz-Flory polydispersity

Woodward, Clifford E. and Forsman, Jan LU (2009) In Journal of Chemical Physics 130(24).
Abstract
We develop a new formulation of polymer self-consistent field theory for polydisperse copolymer fluids satisfying the Schulz-Flory distribution. The result we obtain is remarkably simple and quickly solved numerically. The computational effort scales inversely with the width of the Schulz-Flory distribution. This suggests a significant saving in computational effort when compared with existing approximate solutions of the polymer self-consistent field equations for polydispersed systems.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
SCF calculations, polymer solutions, liquid theory, polymer blends
in
Journal of Chemical Physics
volume
130
issue
24
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000267600400036
  • scopus:67650502140
ISSN
0021-9606
DOI
10.1063/1.3153921
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
id
3d47b312-f88d-4f67-aa76-f95e09247c11 (old id 1463111)
date added to LUP
2016-04-01 11:55:31
date last changed
2021-09-01 04:51:51
@article{3d47b312-f88d-4f67-aa76-f95e09247c11,
  abstract     = {We develop a new formulation of polymer self-consistent field theory for polydisperse copolymer fluids satisfying the Schulz-Flory distribution. The result we obtain is remarkably simple and quickly solved numerically. The computational effort scales inversely with the width of the Schulz-Flory distribution. This suggests a significant saving in computational effort when compared with existing approximate solutions of the polymer self-consistent field equations for polydispersed systems.},
  author       = {Woodward, Clifford E. and Forsman, Jan},
  issn         = {0021-9606},
  language     = {eng},
  number       = {24},
  publisher    = {American Institute of Physics (AIP)},
  series       = {Journal of Chemical Physics},
  title        = {Efficient solution of the self-consistent field theory for block copolymer fluids displaying Schulz-Flory polydispersity},
  url          = {http://dx.doi.org/10.1063/1.3153921},
  doi          = {10.1063/1.3153921},
  volume       = {130},
  year         = {2009},
}