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Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2) by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(eta(2)-CH2=CH2)(MeCN)]

Otto, Stefanus ; Roodt, Andreas and Elding, Lars Ivar LU (2009) In Inorganic Chemistry Communications 12(8). p.766-768
Abstract
Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2), 1, by L in dichloromethane yields trans-[PtCl2(eta(2)-CH2=CH2)(L)] (L = THF, 2, or MeCN, 3) with bridge-splitting equilibrium constants of 0.0289 +/- 0.0007 and 3601 +/- 215 mol(-1) dm(3), respectively, as determined by UV/Vis measurements. The reaction of 3 in MeCN with Cl- is essentially quantitative. The crystal structure of trans-[PtCl2(eta(2)-CH2=CH2)(CH3CN)] is reported. (C) 2009 Elsevier B.V. All rights reserved.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Equilibrium constants, Ethene, Platinum, Zeise, Crystal structure
in
Inorganic Chemistry Communications
volume
12
issue
8
pages
3 pages
publisher
Elsevier
external identifiers
  • wos:000269400000018
  • scopus:67651222104
ISSN
1879-0259
DOI
10.1016/j.inoche.2009.06.010
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
238c2fcb-661a-48f5-b59d-28a1592c1c4a (old id 1476306)
date added to LUP
2016-04-01 11:49:22
date last changed
2021-05-05 05:47:29
@article{238c2fcb-661a-48f5-b59d-28a1592c1c4a,
  abstract     = {Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2), 1, by L in dichloromethane yields trans-[PtCl2(eta(2)-CH2=CH2)(L)] (L = THF, 2, or MeCN, 3) with bridge-splitting equilibrium constants of 0.0289 +/- 0.0007 and 3601 +/- 215 mol(-1) dm(3), respectively, as determined by UV/Vis measurements. The reaction of 3 in MeCN with Cl- is essentially quantitative. The crystal structure of trans-[PtCl2(eta(2)-CH2=CH2)(CH3CN)] is reported. (C) 2009 Elsevier B.V. All rights reserved.},
  author       = {Otto, Stefanus and Roodt, Andreas and Elding, Lars Ivar},
  issn         = {1879-0259},
  language     = {eng},
  number       = {8},
  pages        = {766--768},
  publisher    = {Elsevier},
  series       = {Inorganic Chemistry Communications},
  title        = {Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2) by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(eta(2)-CH2=CH2)(MeCN)]},
  url          = {http://dx.doi.org/10.1016/j.inoche.2009.06.010},
  doi          = {10.1016/j.inoche.2009.06.010},
  volume       = {12},
  year         = {2009},
}