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Structure and Bonding of Ethylene Oxide on Si(100)

Hennies, Franz LU ; Bao, Z.; Travnikova, O. and Piancastelli, M. N. (2009) In Journal of Physical Chemistry C 113(36). p.16077-16082
Abstract
The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Physical Chemistry C
volume
113
issue
36
pages
16077 - 16082
publisher
The American Chemical Society
external identifiers
  • wos:000269654700046
  • scopus:70349098435
ISSN
1932-7447
DOI
10.1021/jp9030859
language
English
LU publication?
yes
id
2bc6c5eb-de7f-4b19-957e-eb094a3843dd (old id 1492327)
date added to LUP
2009-10-16 16:22:24
date last changed
2017-01-01 04:40:28
@article{2bc6c5eb-de7f-4b19-957e-eb094a3843dd,
  abstract     = {The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.},
  author       = {Hennies, Franz and Bao, Z. and Travnikova, O. and Piancastelli, M. N.},
  issn         = {1932-7447},
  language     = {eng},
  number       = {36},
  pages        = {16077--16082},
  publisher    = {The American Chemical Society},
  series       = {Journal of Physical Chemistry C},
  title        = {Structure and Bonding of Ethylene Oxide on Si(100)},
  url          = {http://dx.doi.org/10.1021/jp9030859},
  volume       = {113},
  year         = {2009},
}