Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Structure and Bonding of Ethylene Oxide on Si(100)

Hennies, Franz LU ; Bao, Z. ; Travnikova, O. and Piancastelli, M. N. (2009) In Journal of Physical Chemistry C 113(36). p.16077-16082
Abstract
The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Physical Chemistry C
volume
113
issue
36
pages
16077 - 16082
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000269654700046
  • scopus:70349098435
ISSN
1932-7447
DOI
10.1021/jp9030859
language
English
LU publication?
yes
id
2bc6c5eb-de7f-4b19-957e-eb094a3843dd (old id 1492327)
date added to LUP
2016-04-01 11:55:40
date last changed
2022-02-25 23:24:25
@article{2bc6c5eb-de7f-4b19-957e-eb094a3843dd,
  abstract     = {{The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.}},
  author       = {{Hennies, Franz and Bao, Z. and Travnikova, O. and Piancastelli, M. N.}},
  issn         = {{1932-7447}},
  language     = {{eng}},
  number       = {{36}},
  pages        = {{16077--16082}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Journal of Physical Chemistry C}},
  title        = {{Structure and Bonding of Ethylene Oxide on Si(100)}},
  url          = {{http://dx.doi.org/10.1021/jp9030859}},
  doi          = {{10.1021/jp9030859}},
  volume       = {{113}},
  year         = {{2009}},
}