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Selective hydrogen bond disruption in adenine monolayer films by reaction with water

Doherty, W. J., III; Ristinmaa Sörensen, Stacey LU and Friedlein, R. (2009) In Journal of Electron Spectroscopy and Related Phenomena 174(1-3). p.107-109
Abstract
High-resolution X-ray photoelectron spectroscopy of two-dimensional films of adenine on a highly oriented pyrolitic graphite [0 0 0 1] surface reveal bonding changes induced by exposure to water. The hydrogen-bond interactions between adenine molecules were replaced by adenine-water hydrogen bonds in a stepwise pattern. This reaction destroyed the film network and changed the chemical state of the nitrogen sites. The reaction with water molecules affected both the donor and acceptor states of the oxygen atoms, as compared to those in water. (C) 2009 Elsevier B.V. All rights reserved.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Self-assembly, Organic monolayer, Hydrogen bonding, spectroscopy, Photoelectron
in
Journal of Electron Spectroscopy and Related Phenomena
volume
174
issue
1-3
pages
107 - 109
publisher
Elsevier
external identifiers
  • wos:000271347700018
  • scopus:70349213717
ISSN
0368-2048
DOI
10.1016/j.elspec.2009.05.001
language
English
LU publication?
yes
id
a0d73db8-cc6d-4a23-af82-62e708f618ea (old id 1505013)
date added to LUP
2009-11-24 17:04:50
date last changed
2017-01-01 06:10:07
@article{a0d73db8-cc6d-4a23-af82-62e708f618ea,
  abstract     = {High-resolution X-ray photoelectron spectroscopy of two-dimensional films of adenine on a highly oriented pyrolitic graphite [0 0 0 1] surface reveal bonding changes induced by exposure to water. The hydrogen-bond interactions between adenine molecules were replaced by adenine-water hydrogen bonds in a stepwise pattern. This reaction destroyed the film network and changed the chemical state of the nitrogen sites. The reaction with water molecules affected both the donor and acceptor states of the oxygen atoms, as compared to those in water. (C) 2009 Elsevier B.V. All rights reserved.},
  author       = {Doherty, W. J., III and Ristinmaa Sörensen, Stacey and Friedlein, R.},
  issn         = {0368-2048},
  keyword      = {Self-assembly,Organic monolayer,Hydrogen bonding,spectroscopy,Photoelectron},
  language     = {eng},
  number       = {1-3},
  pages        = {107--109},
  publisher    = {Elsevier},
  series       = {Journal of Electron Spectroscopy and Related Phenomena},
  title        = {Selective hydrogen bond disruption in adenine monolayer films by reaction with water},
  url          = {http://dx.doi.org/10.1016/j.elspec.2009.05.001},
  volume       = {174},
  year         = {2009},
}