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Solution and structural studies of the Cd(II) - Aconitate system

Kostakis, George; Malandrinos, Gerasimos; Nordlander, Ebbe LU ; Haukka, Matti and Plakatouras, John C. (2009) In Polyhedron 28(15). p.3227-3234
Abstract
The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Topology, Coordination polymers, Lewis base, Potentiometry, Cadmium complexes
in
Polyhedron
volume
28
issue
15
pages
3227 - 3234
publisher
Elsevier
external identifiers
  • wos:000271144200010
  • scopus:70349448546
ISSN
0277-5387
DOI
10.1016/j.poly.2009.05.008
language
English
LU publication?
yes
id
e019bca8-3be3-4c91-9cd5-d503e5fa5ab7 (old id 1505311)
date added to LUP
2009-11-24 12:53:00
date last changed
2017-05-28 04:11:14
@article{e019bca8-3be3-4c91-9cd5-d503e5fa5ab7,
  abstract     = {The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.},
  author       = {Kostakis, George and Malandrinos, Gerasimos and Nordlander, Ebbe and Haukka, Matti and Plakatouras, John C.},
  issn         = {0277-5387},
  keyword      = {Topology,Coordination polymers,Lewis base,Potentiometry,Cadmium complexes},
  language     = {eng},
  number       = {15},
  pages        = {3227--3234},
  publisher    = {Elsevier},
  series       = {Polyhedron},
  title        = {Solution and structural studies of the Cd(II) - Aconitate system},
  url          = {http://dx.doi.org/10.1016/j.poly.2009.05.008},
  volume       = {28},
  year         = {2009},
}