Porous polymaleimide networks
Jannasch, Patric LU
(2001)
In Journal of Materials Chemistry
11(9).
p.2303-2306
- Abstract
- Porous network structures were prepared by in situ polymerisation of a mixture of N-phenylmaleimide and 1, 1'-(methylenedi-4,1-plienylene)bismaleimide (95:5 w/w) in poly(vinylidene difluoride-co-hexafluoropropylene) (PVDH). The mixture of the maleimide monomers was found to form thermoreversible gels with PVDH. Thermodynamic analysis of the gelation process using calorimetry data indicated the formation of complexes of N-phenylmaleimide and vinylidene difluoride repeat units with a molar ratio of 1:2, respectively. PVDH formed optically clear solutions in the mixture above the gelation temperature, observed at 80-120 degreesC depending on composition. Polymerisation of the maleimides was induced by increasing the temperature to 250... (More)
- Porous network structures were prepared by in situ polymerisation of a mixture of N-phenylmaleimide and 1, 1'-(methylenedi-4,1-plienylene)bismaleimide (95:5 w/w) in poly(vinylidene difluoride-co-hexafluoropropylene) (PVDH). The mixture of the maleimide monomers was found to form thermoreversible gels with PVDH. Thermodynamic analysis of the gelation process using calorimetry data indicated the formation of complexes of N-phenylmaleimide and vinylidene difluoride repeat units with a molar ratio of 1:2, respectively. PVDH formed optically clear solutions in the mixture above the gelation temperature, observed at 80-120 degreesC depending on composition. Polymerisation of the maleimides was induced by increasing the temperature to 250 degreesC. During polymerisation, the resulting polymaleimide phase separated from the PVDH melt. A morphological study by microscopy revealed that blends with 80 wt% PVDH contained continuous networks of crosslinked polymaleimide. The porous networks were collected after removing the PVDH by solvent extraction. Thermogravimetrical analysis of the polymaleimide networks under N-2 atmosphere showed that the onset of weight loss occurred at 380 degreesC. These networks may thus be used to prepare thermally stable membranes. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/150797
- author
- Jannasch, Patric
LU
- organization
- publishing date
- 2001
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Materials Chemistry
- volume
- 11
- issue
- 9
- pages
- 2303 - 2306
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:0034849629
- ISSN
- 1364-5501
- DOI
- 10.1039/b105152k
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- e80e0b67-73b2-4aed-85a9-873e2f0bda25 (old id 150797)
- date added to LUP
- 2016-04-01 12:38:13
- date last changed
- 2022-01-27 07:50:22
@article{e80e0b67-73b2-4aed-85a9-873e2f0bda25,
abstract = {{Porous network structures were prepared by in situ polymerisation of a mixture of N-phenylmaleimide and 1, 1'-(methylenedi-4,1-plienylene)bismaleimide (95:5 w/w) in poly(vinylidene difluoride-co-hexafluoropropylene) (PVDH). The mixture of the maleimide monomers was found to form thermoreversible gels with PVDH. Thermodynamic analysis of the gelation process using calorimetry data indicated the formation of complexes of N-phenylmaleimide and vinylidene difluoride repeat units with a molar ratio of 1:2, respectively. PVDH formed optically clear solutions in the mixture above the gelation temperature, observed at 80-120 degreesC depending on composition. Polymerisation of the maleimides was induced by increasing the temperature to 250 degreesC. During polymerisation, the resulting polymaleimide phase separated from the PVDH melt. A morphological study by microscopy revealed that blends with 80 wt% PVDH contained continuous networks of crosslinked polymaleimide. The porous networks were collected after removing the PVDH by solvent extraction. Thermogravimetrical analysis of the polymaleimide networks under N-2 atmosphere showed that the onset of weight loss occurred at 380 degreesC. These networks may thus be used to prepare thermally stable membranes.}},
author = {{Jannasch, Patric}},
issn = {{1364-5501}},
language = {{eng}},
number = {{9}},
pages = {{2303--2306}},
publisher = {{Royal Society of Chemistry}},
series = {{Journal of Materials Chemistry}},
title = {{Porous polymaleimide networks}},
url = {{http://dx.doi.org/10.1039/b105152k}},
doi = {{10.1039/b105152k}},
volume = {{11}},
year = {{2001}},
}