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Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection

Liu, Jing-fu LU ; Li, N; Jiang, G B; Li, JM; Jönsson, Jan Åke LU and Wen, M J (2005) In Journal of Chromatography A 1066(1-2). p.27-32
Abstract
Solid-phase microextraction (SPME) with a disposable ionic liquid (IL) coating was developed for headspace extraction of benzene, toluene, ethylbenzene, and xylenes (BTEX) in paints. The SPME fiber was coated with IL prior to every extraction, then the analytes were extracted and desorbed on the injection port of gas chromatography, and finally the IL coating on the fiber was washed out with solvents. The coating and washing out of IL from the fiber can be finished in a few minutes. This disposable IL-coated fiber was applied to determine BTEX in water-soluble paints with results in good agreement with that obtained by using commercially available SPME fibers. For all the four studied paints samples, the benzene contents were under the... (More)
Solid-phase microextraction (SPME) with a disposable ionic liquid (IL) coating was developed for headspace extraction of benzene, toluene, ethylbenzene, and xylenes (BTEX) in paints. The SPME fiber was coated with IL prior to every extraction, then the analytes were extracted and desorbed on the injection port of gas chromatography, and finally the IL coating on the fiber was washed out with solvents. The coating and washing out of IL from the fiber can be finished in a few minutes. This disposable IL-coated fiber was applied to determine BTEX in water-soluble paints with results in good agreement with that obtained by using commercially available SPME fibers. For all the four studied paints samples, the benzene contents were under the detection limits, but relatively high contents of toluene, ethylbenzene and xylenes (56-271 mug g(-1)) were detected with spiked recoveries in the range of 70-114%. Compared to the widely used commercially available SPME fibers, this proposed disposable IL-coated fiber has much lower cost per determination, comparable reproducibility (RSD < 11%), and no carryover between each determination. Considering that IL possess good extractability for various organic compounds and metals ions, and that task-specific IL can be designed and synthesized for selective extraction of target analytes, this disposable IL coating SPME might has great potential in sample preparation. (C) 2005 Elsevier B.V. All rights reserved. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chromatography A
volume
1066
issue
1-2
pages
27 - 32
publisher
Elsevier
external identifiers
  • wos:000227503600004
  • pmid:15794551
  • scopus:14144251196
ISSN
0021-9673
DOI
10.1016/j.chroma.2005.01.024
language
English
LU publication?
yes
id
89156cbb-2759-423f-8339-192cf86de333 (old id 151106)
date added to LUP
2007-06-27 10:33:23
date last changed
2017-11-05 04:30:17
@article{89156cbb-2759-423f-8339-192cf86de333,
  abstract     = {Solid-phase microextraction (SPME) with a disposable ionic liquid (IL) coating was developed for headspace extraction of benzene, toluene, ethylbenzene, and xylenes (BTEX) in paints. The SPME fiber was coated with IL prior to every extraction, then the analytes were extracted and desorbed on the injection port of gas chromatography, and finally the IL coating on the fiber was washed out with solvents. The coating and washing out of IL from the fiber can be finished in a few minutes. This disposable IL-coated fiber was applied to determine BTEX in water-soluble paints with results in good agreement with that obtained by using commercially available SPME fibers. For all the four studied paints samples, the benzene contents were under the detection limits, but relatively high contents of toluene, ethylbenzene and xylenes (56-271 mug g(-1)) were detected with spiked recoveries in the range of 70-114%. Compared to the widely used commercially available SPME fibers, this proposed disposable IL-coated fiber has much lower cost per determination, comparable reproducibility (RSD &lt; 11%), and no carryover between each determination. Considering that IL possess good extractability for various organic compounds and metals ions, and that task-specific IL can be designed and synthesized for selective extraction of target analytes, this disposable IL coating SPME might has great potential in sample preparation. (C) 2005 Elsevier B.V. All rights reserved.},
  author       = {Liu, Jing-fu and Li, N and Jiang, G B and Li, JM and Jönsson, Jan Åke and Wen, M J},
  issn         = {0021-9673},
  language     = {eng},
  number       = {1-2},
  pages        = {27--32},
  publisher    = {Elsevier},
  series       = {Journal of Chromatography A},
  title        = {Disposable ionic liquid coating for headspace solid-phase microextraction of benzene, toluene, ethylbenzene. and xylenes in paints followed by gas chromatography-flame ionization detection},
  url          = {http://dx.doi.org/10.1016/j.chroma.2005.01.024},
  volume       = {1066},
  year         = {2005},
}