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Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

Johansson, Roger LU ; Jarenmark, Martin LU and Wendt, Ola LU (2005) In Organometallics 24(19). p.4500-4502
Abstract
A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
24
issue
19
pages
4500 - 4502
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000231784200002
  • scopus:25444468604
ISSN
1520-6041
DOI
10.1021/om0505561
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)
id
4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f (old id 151835)
date added to LUP
2016-04-01 12:04:01
date last changed
2020-05-06 02:31:50
@article{4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f,
  abstract     = {A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.},
  author       = {Johansson, Roger and Jarenmark, Martin and Wendt, Ola},
  issn         = {1520-6041},
  language     = {eng},
  number       = {19},
  pages        = {4500--4502},
  publisher    = {The American Chemical Society (ACS)},
  series       = {Organometallics},
  title        = {Insertion of carbon dioxide into (PCP)Pd-II-Me bonds},
  url          = {http://dx.doi.org/10.1021/om0505561},
  doi          = {10.1021/om0505561},
  volume       = {24},
  year         = {2005},
}