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Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

Johansson, Roger LU ; Jarenmark, Martin LU and Wendt, Ola LU (2005) In Organometallics 24(19). p.4500-4502
Abstract
A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
24
issue
19
pages
4500 - 4502
publisher
The American Chemical Society
external identifiers
  • wos:000231784200002
  • scopus:25444468604
ISSN
1520-6041
DOI
10.1021/om0505561
language
English
LU publication?
yes
id
4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f (old id 151835)
date added to LUP
2007-07-10 11:51:34
date last changed
2017-11-12 03:25:05
@article{4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f,
  abstract     = {A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.},
  author       = {Johansson, Roger and Jarenmark, Martin and Wendt, Ola},
  issn         = {1520-6041},
  language     = {eng},
  number       = {19},
  pages        = {4500--4502},
  publisher    = {The American Chemical Society},
  series       = {Organometallics},
  title        = {Insertion of carbon dioxide into (PCP)Pd-II-Me bonds},
  url          = {http://dx.doi.org/10.1021/om0505561},
  volume       = {24},
  year         = {2005},
}