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Azinyl sulfides. LXXXI. 14-Phenyl-7-thiapyrano[2,3-c;6,5-c ']diquinoline-14-carbonitrile

Besnard, Céline LU ; Kloc, C; Siegrist, Theo LU ; Svensson, Christer LU and Pluta, K (2005) In Acta Crystallographica. Section C: Crystal Structure Communications 61(Pt 6). p.377-379
Abstract
The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 ( 7)degrees. The 14- phenyl substituent is in a quasi- axial conformation, while the 14-cyano substituent is in a quasi- equatorial conformation with respect to the thiopyran ring. The S center dot center dot center dot C - C-phenyl and S center dot center dot center dot C - C-CN angles are 116.8 ( 2) and 129.3 ( 2) degrees, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
61
issue
Pt 6
pages
377 - 379
publisher
International Union of Crystallography
external identifiers
  • wos:000229464200039
  • scopus:30344468119
ISSN
0108-2701
DOI
10.1107/S0108270105009832
language
English
LU publication?
yes
id
faa4880a-c9f4-4c80-bbfb-00437b83294d (old id 152198)
date added to LUP
2007-07-12 16:09:13
date last changed
2017-01-01 06:41:25
@article{faa4880a-c9f4-4c80-bbfb-00437b83294d,
  abstract     = {The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 ( 7)degrees. The 14- phenyl substituent is in a quasi- axial conformation, while the 14-cyano substituent is in a quasi- equatorial conformation with respect to the thiopyran ring. The S center dot center dot center dot C - C-phenyl and S center dot center dot center dot C - C-CN angles are 116.8 ( 2) and 129.3 ( 2) degrees, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system.},
  author       = {Besnard, Céline and Kloc, C and Siegrist, Theo and Svensson, Christer and Pluta, K},
  issn         = {0108-2701},
  language     = {eng},
  number       = {Pt 6},
  pages        = {377--379},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica. Section C: Crystal Structure Communications},
  title        = {Azinyl sulfides. LXXXI. 14-Phenyl-7-thiapyrano[2,3-c;6,5-c ']diquinoline-14-carbonitrile},
  url          = {http://dx.doi.org/10.1107/S0108270105009832},
  volume       = {61},
  year         = {2005},
}