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{mu-2-[1-(N,N-Dimethylamino)ethyl]ferrocene-1,1 '-diylbis(diphenylphosphine)-kappa P-2 : P '}-bis[chlorogold(I)]

Sam, Z A; Oskarsson, Åke LU ; Elmroth, Sofi LU and Roodt, Andreas (2005) In Acta Crystallographica Section E: Structure Reports Online 61(10). p.2090-2092
Abstract
The structure of the title compound, [ Au2Fe( C21H23NP)( C17H14P) Cl-2], displays the pseudo-linear [ P - Au - Cl = 175.4 ( 1) and 174.0 ( 1) degrees] two-coordinate geometry usually observed in gold( I) complexes. The Au - P bond distances are 2.237 ( 2) and 2.224 ( 2) angstrom and the Au - Cl distances are 2.271 ( 3) and 2.278 ( 2) angstrom. The bis( diphenylphosphino)ferrocenyl ligand links the gold metal centres in a bidentate fashion via the ferrocene group, thus leading to a binuclear gold system.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
61
issue
10
pages
2090 - 2092
publisher
Wiley-Blackwell
external identifiers
  • wos:000232301100080
  • scopus:33144465227
ISSN
1600-5368
DOI
10.1107/S1600536805029582
language
English
LU publication?
yes
id
eaad8a69-f3fb-4a94-b22d-3ea3b5b65d2d (old id 152319)
date added to LUP
2007-07-06 14:58:04
date last changed
2017-01-01 06:46:47
@article{eaad8a69-f3fb-4a94-b22d-3ea3b5b65d2d,
  abstract     = {The structure of the title compound, [ Au2Fe( C21H23NP)( C17H14P) Cl-2], displays the pseudo-linear [ P - Au - Cl = 175.4 ( 1) and 174.0 ( 1) degrees] two-coordinate geometry usually observed in gold( I) complexes. The Au - P bond distances are 2.237 ( 2) and 2.224 ( 2) angstrom and the Au - Cl distances are 2.271 ( 3) and 2.278 ( 2) angstrom. The bis( diphenylphosphino)ferrocenyl ligand links the gold metal centres in a bidentate fashion via the ferrocene group, thus leading to a binuclear gold system.},
  author       = {Sam, Z A and Oskarsson, Åke and Elmroth, Sofi and Roodt, Andreas},
  issn         = {1600-5368},
  language     = {eng},
  number       = {10},
  pages        = {2090--2092},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {{mu-2-[1-(N,N-Dimethylamino)ethyl]ferrocene-1,1 '-diylbis(diphenylphosphine)-kappa P-2 : P '}-bis[chlorogold(I)]},
  url          = {http://dx.doi.org/10.1107/S1600536805029582},
  volume       = {61},
  year         = {2005},
}