Advanced

A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue

Hansson, Anna LU ; Wixe, Torbjörn ; Bergquist, Karl-Erik LU and Wärnmark, Kenneth LU (2005) In Organic Letters 7(10). p.2019-2022
Abstract
A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organic Letters
volume
7
issue
10
pages
2019 - 2022
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000228984500034
  • pmid:15876044
  • scopus:19544384188
  • pmid:15876044
ISSN
1523-7052
DOI
10.1021/ol050513g
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
97fdff39-2ef8-40a3-8849-50ad39f86e06 (old id 152404)
date added to LUP
2016-04-01 12:29:24
date last changed
2020-01-12 09:55:37
@article{97fdff39-2ef8-40a3-8849-50ad39f86e06,
  abstract     = {A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.},
  author       = {Hansson, Anna and Wixe, Torbjörn and Bergquist, Karl-Erik and Wärnmark, Kenneth},
  issn         = {1523-7052},
  language     = {eng},
  number       = {10},
  pages        = {2019--2022},
  publisher    = {The American Chemical Society (ACS)},
  series       = {Organic Letters},
  title        = {A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue},
  url          = {http://dx.doi.org/10.1021/ol050513g},
  doi          = {10.1021/ol050513g},
  volume       = {7},
  year         = {2005},
}