Synthesis of 2-pyridone-fused 2,2 '-bipyridine derivatives. An unexpectedly complex solid state structure of 3,6-dimethyl-9H-4,5,9-triazaphenanthren-10-one
(2005) In Organic and Biomolecular Chemistry 3(6). p.996-1001- Abstract
- 2- Pyridone- fused 2,2'- bipyridine derivatives 1a and 1b were synthesised. X- Ray diffraction analysis of 1b revealed a highly complex solid state structure with a disordered molecule imbedded in a channel structure formed by a centrosymmetric lattice of hexagonally packed, hydrogen bonded columns. The columns are assembled from three symmetry independent molecules. Dimerisation of the self- complementary cis- amide hydrogen bond motif is overridden by the fulfilment of the proton coordination ability of the phenanthroline nitrogens in accordance with Etter's rules of hydrogen bond priorities.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/152421
- author
- Jonsson, Stefan LU ; Solano, Carlos LU ; Wendt, Ola LU ; Siegel, Jay S and Wärnmark, Kenneth LU
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Organic and Biomolecular Chemistry
- volume
- 3
- issue
- 6
- pages
- 996 - 1001
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000227454700008
- pmid:15750641
- scopus:16244378225
- pmid:15750641
- ISSN
- 1477-0539
- DOI
- 10.1039/b417485b
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- ee72ba30-f204-4bf0-9d91-3935db3e1ea3 (old id 152421)
- date added to LUP
- 2016-04-01 12:24:04
- date last changed
- 2022-01-27 03:16:20
@article{ee72ba30-f204-4bf0-9d91-3935db3e1ea3, abstract = {{2- Pyridone- fused 2,2'- bipyridine derivatives 1a and 1b were synthesised. X- Ray diffraction analysis of 1b revealed a highly complex solid state structure with a disordered molecule imbedded in a channel structure formed by a centrosymmetric lattice of hexagonally packed, hydrogen bonded columns. The columns are assembled from three symmetry independent molecules. Dimerisation of the self- complementary cis- amide hydrogen bond motif is overridden by the fulfilment of the proton coordination ability of the phenanthroline nitrogens in accordance with Etter's rules of hydrogen bond priorities.}}, author = {{Jonsson, Stefan and Solano, Carlos and Wendt, Ola and Siegel, Jay S and Wärnmark, Kenneth}}, issn = {{1477-0539}}, language = {{eng}}, number = {{6}}, pages = {{996--1001}}, publisher = {{Royal Society of Chemistry}}, series = {{Organic and Biomolecular Chemistry}}, title = {{Synthesis of 2-pyridone-fused 2,2 '-bipyridine derivatives. An unexpectedly complex solid state structure of 3,6-dimethyl-9H-4,5,9-triazaphenanthren-10-one}}, url = {{http://dx.doi.org/10.1039/b417485b}}, doi = {{10.1039/b417485b}}, volume = {{3}}, year = {{2005}}, }