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Synthesis and characterization of poly(ethylene oxide-co-ethylene carbonate) macromonomers and their use in the preparation of crosslinked polymer electrolytes

Munch Elmér, Anette LU and Jannasch, Patric LU orcid (2006) In Journal of Polymer Science. Part A, Polymer Chemistry 44(7). p.2195-2205
Abstract
Methacrylate-functionalized poly(ethylene oxide-co-ethylene carbonate) macromonomers were prepared in two steps by the anionic ring-opening polymerization of ethylene carbonate at 180 °C, with potassium methoxide as the initiator, followed by the reaction of the terminal hydroxyl groups of the polymers with methacryloyl chloride. The molecular weight of the polymer went through a maximum after approximately 45 min of polymerization, and the content of ethylene carbonate units in the polymer decreased with the reaction time. A polymer having a number-average molecular weight of 2650 g mol-1 and an ethylene carbonate content of 28 mol % was selected and used to prepare a macromonomer, which was subsequently polymerized by UV irradiation in... (More)
Methacrylate-functionalized poly(ethylene oxide-co-ethylene carbonate) macromonomers were prepared in two steps by the anionic ring-opening polymerization of ethylene carbonate at 180 °C, with potassium methoxide as the initiator, followed by the reaction of the terminal hydroxyl groups of the polymers with methacryloyl chloride. The molecular weight of the polymer went through a maximum after approximately 45 min of polymerization, and the content of ethylene carbonate units in the polymer decreased with the reaction time. A polymer having a number-average molecular weight of 2650 g mol-1 and an ethylene carbonate content of 28 mol % was selected and used to prepare a macromonomer, which was subsequently polymerized by UV irradiation in the presence of different concentrations of lithium bis(trifluoromethanesulfonyl)imide salt. The resulting self-supportive crosslinked polymer electrolyte membranes reached ionic conductivities of 6.3 × 10-6 S cm-1 at 20 °C. The coordination of the lithium ions by both the ether and carbonate oxygens in the polymer structure was indicated by Fourier transform infrared spectroscopy. (Less)
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type
Contribution to journal
publication status
published
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in
Journal of Polymer Science. Part A, Polymer Chemistry
volume
44
issue
7
pages
2195 - 2205
publisher
John Wiley and Sons
external identifiers
  • wos:000236197800005
  • scopus:33646494212
ISSN
0887-624X
DOI
10.1002/pola.21324
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
2a5de8e1-fcd6-42f2-b007-582d1b513d86 (old id 153325)
date added to LUP
2016-04-01 16:16:15
date last changed
2021-09-22 02:42:59
@article{2a5de8e1-fcd6-42f2-b007-582d1b513d86,
  abstract     = {Methacrylate-functionalized poly(ethylene oxide-co-ethylene carbonate) macromonomers were prepared in two steps by the anionic ring-opening polymerization of ethylene carbonate at 180 °C, with potassium methoxide as the initiator, followed by the reaction of the terminal hydroxyl groups of the polymers with methacryloyl chloride. The molecular weight of the polymer went through a maximum after approximately 45 min of polymerization, and the content of ethylene carbonate units in the polymer decreased with the reaction time. A polymer having a number-average molecular weight of 2650 g mol-1 and an ethylene carbonate content of 28 mol % was selected and used to prepare a macromonomer, which was subsequently polymerized by UV irradiation in the presence of different concentrations of lithium bis(trifluoromethanesulfonyl)imide salt. The resulting self-supportive crosslinked polymer electrolyte membranes reached ionic conductivities of 6.3 × 10-6 S cm-1 at 20 °C. The coordination of the lithium ions by both the ether and carbonate oxygens in the polymer structure was indicated by Fourier transform infrared spectroscopy.},
  author       = {Munch Elmér, Anette and Jannasch, Patric},
  issn         = {0887-624X},
  language     = {eng},
  number       = {7},
  pages        = {2195--2205},
  publisher    = {John Wiley and Sons},
  series       = {Journal of Polymer Science. Part A, Polymer Chemistry},
  title        = {Synthesis and characterization of poly(ethylene oxide-co-ethylene carbonate) macromonomers and their use in the preparation of crosslinked polymer electrolytes},
  url          = {http://dx.doi.org/10.1002/pola.21324},
  doi          = {10.1002/pola.21324},
  volume       = {44},
  year         = {2006},
}