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Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Jarenmark, Martin LU ; Carlsson, Hakan; Trukhan, Vladimir LU ; Haukka, Matti; Canton, Sophie LU ; Walczak, Monica; Fullagar, Wilfred LU ; Sundström, Villy LU and Nordlander, Ebbe LU (2010) In Inorganic Chemistry Communications 13(3). p.334-337
Abstract
The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Transesterification, Model complexes, phosphatase, Purple acid, Dinuclear, Bioinorganic chemistry, Heterodinuclear, Zinc, Iron, HPNP
in
Inorganic Chemistry Communications
volume
13
issue
3
pages
334 - 337
publisher
Elsevier
external identifiers
  • wos:000275765600002
  • scopus:76749093692
ISSN
1879-0259
DOI
10.1016/j.inoche.2009.12.007
language
English
LU publication?
yes
id
796a5f76-d649-47a9-8e92-450d5d317a54 (old id 1587998)
date added to LUP
2010-04-22 11:32:12
date last changed
2018-05-29 12:19:49
@article{796a5f76-d649-47a9-8e92-450d5d317a54,
  abstract     = {The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved},
  author       = {Jarenmark, Martin and Carlsson, Hakan and Trukhan, Vladimir and Haukka, Matti and Canton, Sophie and Walczak, Monica and Fullagar, Wilfred and Sundström, Villy and Nordlander, Ebbe},
  issn         = {1879-0259},
  keyword      = {Transesterification,Model complexes,phosphatase,Purple acid,Dinuclear,Bioinorganic chemistry,Heterodinuclear,Zinc,Iron,HPNP},
  language     = {eng},
  number       = {3},
  pages        = {334--337},
  publisher    = {Elsevier},
  series       = {Inorganic Chemistry Communications},
  title        = {Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases},
  url          = {http://dx.doi.org/10.1016/j.inoche.2009.12.007},
  volume       = {13},
  year         = {2010},
}