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Hygroscopic properties of Amazonian biomass burning and European background HULIS and investigation of their effects on surface tension with two models linking H-TDMA to CCNC data

Fors, Erik LU ; Rissler, Jenny LU ; Massling, A.; Svenningsson, Birgitta LU ; Andreae, M. O.; Dusek, U.; Frank, Göran LU ; Hoffer, A.; Bilde, M. and Kiss, G., et al. (2010) In Atmospheric Chemistry and Physics 10(12). p.5625-5639
Abstract
HUmic-LIke Substances (HULIS) have been identified as major contributors to the organic carbon in atmospheric aerosol. The term "HULIS" is used to describe the organic material found in aerosol particles that resembles the humic organic material in rivers and sea water and in soils. In this study, two sets of filter samples from atmospheric aerosols were collected at different sites. One set of samples was collected at the K-puszta rural site in Hungary, about 80 km SE of Budapest, and a second was collected at a site in Rondonia, Amazonia, Brazil, during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia - Smoke Aerosols, Clouds, Rainfall and Climate (LBA-SMOCC) biomass burning season experiment. HULIS were extracted from the... (More)
HUmic-LIke Substances (HULIS) have been identified as major contributors to the organic carbon in atmospheric aerosol. The term "HULIS" is used to describe the organic material found in aerosol particles that resembles the humic organic material in rivers and sea water and in soils. In this study, two sets of filter samples from atmospheric aerosols were collected at different sites. One set of samples was collected at the K-puszta rural site in Hungary, about 80 km SE of Budapest, and a second was collected at a site in Rondonia, Amazonia, Brazil, during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia - Smoke Aerosols, Clouds, Rainfall and Climate (LBA-SMOCC) biomass burning season experiment. HULIS were extracted from the samples and their hygroscopic properties were studied using a Hygroscopicity Tandem Differential Mobility Analyzer (H-TDMA) at relative humidity (RH) < 100%, and a cloud condensation nucleus counter (CCNC) at RH > 100%. The H-TDMA measurements were carried out at a dry diameter of 100 nm and for RH ranging from 30 to 98%. At 90% RH the HULIS samples showed diameter growth factors between 1.04 and 1.07, reaching values of 1.4 at 98% RH. The cloud nucleating properties of the two sets of aerosol samples were analysed using two types of thermal static cloud condensation nucleus counters. Two different parameterization models were applied to investigate the potential effect of HULIS surface activity, both yielding similar results. For the K-puszta winter HULIS sample, the surface tension at the point of activation was estimated to be lowered by between 34% (47.7 mN/m) and 31% (50.3 mN/m) for dry sizes between 50 and 120 nm in comparison to pure water. A moderate lowering was also observed for the entire water soluble aerosol sample, including both organic and inorganic compounds, where the surface tension was decreased by between 2% (71.2 mN/m) and 13% (63.3 mN/m). (Less)
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Atmospheric Chemistry and Physics
volume
10
issue
12
pages
5625 - 5639
publisher
Copernicus Gesellschaft Mbh
external identifiers
  • wos:000279391100022
  • scopus:77954096033
ISSN
1680-7324
DOI
10.5194/acp-10-5625-2010
project
MERGE
language
English
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yes
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478481e7-41c7-4b24-9558-02b67431c2ad (old id 1629356)
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2010-07-22 10:52:23
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2018-07-01 03:02:38
@article{478481e7-41c7-4b24-9558-02b67431c2ad,
  abstract     = {HUmic-LIke Substances (HULIS) have been identified as major contributors to the organic carbon in atmospheric aerosol. The term "HULIS" is used to describe the organic material found in aerosol particles that resembles the humic organic material in rivers and sea water and in soils. In this study, two sets of filter samples from atmospheric aerosols were collected at different sites. One set of samples was collected at the K-puszta rural site in Hungary, about 80 km SE of Budapest, and a second was collected at a site in Rondonia, Amazonia, Brazil, during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia - Smoke Aerosols, Clouds, Rainfall and Climate (LBA-SMOCC) biomass burning season experiment. HULIS were extracted from the samples and their hygroscopic properties were studied using a Hygroscopicity Tandem Differential Mobility Analyzer (H-TDMA) at relative humidity (RH) &lt; 100%, and a cloud condensation nucleus counter (CCNC) at RH &gt; 100%. The H-TDMA measurements were carried out at a dry diameter of 100 nm and for RH ranging from 30 to 98%. At 90% RH the HULIS samples showed diameter growth factors between 1.04 and 1.07, reaching values of 1.4 at 98% RH. The cloud nucleating properties of the two sets of aerosol samples were analysed using two types of thermal static cloud condensation nucleus counters. Two different parameterization models were applied to investigate the potential effect of HULIS surface activity, both yielding similar results. For the K-puszta winter HULIS sample, the surface tension at the point of activation was estimated to be lowered by between 34% (47.7 mN/m) and 31% (50.3 mN/m) for dry sizes between 50 and 120 nm in comparison to pure water. A moderate lowering was also observed for the entire water soluble aerosol sample, including both organic and inorganic compounds, where the surface tension was decreased by between 2% (71.2 mN/m) and 13% (63.3 mN/m).},
  author       = {Fors, Erik and Rissler, Jenny and Massling, A. and Svenningsson, Birgitta and Andreae, M. O. and Dusek, U. and Frank, Göran and Hoffer, A. and Bilde, M. and Kiss, G. and Janitsek, S. and Henning, S. and Facchini, M. C. and Decesari, S. and Swietlicki, Erik},
  issn         = {1680-7324},
  language     = {eng},
  number       = {12},
  pages        = {5625--5639},
  publisher    = {Copernicus Gesellschaft Mbh},
  series       = {Atmospheric Chemistry and Physics},
  title        = {Hygroscopic properties of Amazonian biomass burning and European background HULIS and investigation of their effects on surface tension with two models linking H-TDMA to CCNC data},
  url          = {http://dx.doi.org/10.5194/acp-10-5625-2010},
  volume       = {10},
  year         = {2010},
}